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Recombination parameter J 0 PVMD Ren van Swaaij Delft University of Technology Learning objectives How is V oc related to saturation current density, J 0 , and minority carrier lifetime? Relation between J 0 and recombination


  1. Recombination parameter J 0 PVMD René van Swaaij Delft University of Technology

  2. Learning objectives • How is V oc related to saturation current density, J 0 , and minority carrier lifetime? • Relation between J 0 and recombination

  3. Recombination and V oc E Fn Fn eV eV oc oc E Fp Fp

  4. Recombination and V oc E Fn Fn eV eV oc oc E Fp Fp

  5. Recombination and V oc E Fn Fn For: eV eV oc oc E Fp Fp

  6. Recombination and V oc E Fn Fn For: eV eV oc oc E Fp Fp

  7. Recombination and V oc E Fn Fn For: eV eV oc oc E Fp Fp

  8. Recombination and V oc E Fn Fn For: eV eV oc oc E Fp Fp

  9. Recombination and V oc E Fn Fn eV eV oc oc E Fp Fp

  10. Recombination and V oc E Fn Fn eV eV oc oc E Fp Fp

  11. Recombination and V oc E Fn Fn eV eV oc oc E Fp Fp

  12. Recombination and V oc E Fn Fn eV eV oc oc E Fp Fp

  13. Recombination and V oc E Fn Fn eV eV oc oc E Fp Fp V oc depends on recombination rate

  14. Three recombination processes Shockley- Radiative Auger Read-Hall - - - - - - + + +

  15. Surface recombination conduction band E C tr trap states E V valence band x x = = 0, , surface

  16. Total recombination rate p -type 0 W

  17. Total recombination rate p -type 0 W

  18. Total recombination rate p -type 0 W

  19. Generation and recombination in thermal equilibrium • Thermal generation equals thermal recombination - - + +

  20. Generation and recombination in thermal equilibrium • Thermal generation equals thermal recombination for any mechanism - - + +

  21. Recombination rates in thermal equilibrium Radiative Auger SRH Surface

  22. Recombination rates in thermal equilibrium Radiative Auger SRH Surface

  23. Recombination parameter J 0 Radiative Auger SRH Surface

  24. Recombination parameter J 0 Radiative Auger SRH Surface

  25. Recombination parameter J 0 Radiative Auger SRH Surface

  26. Recombination parameter J 0 Radiative Auger SRH Surface

  27. Application J 0 in analysis Ag Ag n + SiN x p-type sc Si p ++ p ++ Al c-Si (200 – 300 μ m)

  28. Application J 0 in analysis Ag Ag n + SiN x J 0,d p-type sc Si p ++ p ++ Al c-Si (200 – 300 μ m)

  29. Application J 0 in analysis Ag Ag n + SiN x J 0,d J 0,Auger J 0,SR SRH p-type sc Si p ++ p ++ Al c-Si (200 – 300 μ m)

  30. Application J 0 in analysis Ag Ag J 0,s,fron ont n + SiN x J 0,d J 0,Auger J 0,SR SRH p-type sc Si p ++ p ++ Al c-Si (200 – 300 μ m)

  31. Summary • V oc is related to saturation current density J 0

  32. Summary • V oc is related to saturation current density J 0 • V oc is related to lifetime  recombination processes

  33. Summary • V oc is related to saturation current density J 0 • V oc is related to lifetime  recombination processes • Recombination processes can be expressed in J 0

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