Pro je c t K ic ko ff Me e ting L AB-SCAL E DE VE L OPME NT - PowerPoint PPT Presentation

Pro je c t K ic ko ff Me e ting L AB-SCAL E DE VE L OPME NT OF A HYBRI D CAPT URE SYST E M WIT H ADVANCE D ME MBRANE , SOL VE NT SYST E M AND PROCE SS INT E GRAT I ON DE -F E 0026464 10/ 29/ 2015

L I S T e a m Pr ofe ssor Hunaid Nulwala – Pr inc ipal Inve stigator • E xpe rie nc e d Che mist with E xpe rie nc e in I ndustry, Go ve rnme nt, a nd Ac a de mia • Stro ng b a c kg ro und in Po lyme rs, I o nic L iq uids, Ga s Se pa ra tio ns • F o unde r o f T wo T e c hno lo g y Co mpa nie s • 40+ Pub lic a tio ns a nd 16+ Pa te nts a nd a pplic a tio ns in Ma te ria l De ve lo pme nt Dr . David L ue bke • Che mic a l E ng ine e r Spe c ia lizing in Ca rb o n Ca pture • F o rme r ORD Ca rb o n Ca pture T e c hnic a l Co o rdina to r • Me mb ra ne Sc ie ntist with E xpe rie nc e De sig ning , Co nstruc ting a nd Ope ra ting Pe rfo rma nc e Syste ms

CCS T e a m Dr . Sc ott Che n Dr . John Pan • E xpe rie nc e d Che mic a l • E xpe rie nc e d Che mic a l E ng ine e r E ng ine e r • Stro ng b a c kg ro und in • Stro ng b a c kg ro und in se pa ra tio n pro c e sse s se pa ra tio n pro c e sse s a nd the rmo dyna mic s • F o unde r o f two te c hnic a l • F o unde r o f Ca rb o n c o mpa nie s Ca pture Sc ie ntific , L L C PSU T e a m Pr ofe ssor Har r y Allc oc k • F a the r o f Pho spha zine Po lyme rs (>630 Artic le s in the Are a ) • Re no wne d Che mist with E xpe rie nc e in I ndustry, Go ve rnme nt a nd Ac a de mia

Pro je c t Org a niza tio n

Pro je c t Ob je c tive s • Simula tio n o f Me mb ra ne a nd So lve nt Sub syste ms • Synthe sis a nd Cha ra c te riza tio n o f T a ilo re d Po lypho spha ze ne s • F a b ric a tio n o f I nte rfa c ia lly-Co ntro lle d E nve lo pe (I CE ) Me mb ra ne s • Optimiza tio n o f Po lyme r, Na no -fille r, a nd F a b ric a tio n Pro c e ss • De sig n a nd Co nstruc tio n o f Me mb ra ne T e st Syste ms • Mo dific a tio n o f Ab so rb e r a nd Strippe r Units o f So lve nt Syste m • Optimiza tio n o f So lve nt Syste m fo r Ope ra tio n in Hyb rid Syste m • De mo nstra tio n o f All Sub syste ms with Simula te d F lue Ga s • Co mple tio n o f Pre limina ry E c o no mic Ana lysis

T e c hnic a l Appro a c h

Pre vio us Me mb ra ne Pro c e ss I nno va tio n (MT R) Pure Me mb ra ne Hyb rid Me mb ra ne

Stra ig htfo rwa rd Pla nt I nte g ra tio n Clean flue gas High Pressure CO2 Air +CO 2 Air Membrane/Absorption Hybrid Process Flue Gas Power Plant Reheated steam FGD IP HP LP Generator Turbine Turbine Turbine Flue gas Super heated ESP steam Induced Fan Makeup Water Air Cold Reheat Boiler Water Feed water Condensate Coal Feed water heat Air Feed water Pump exchangers

T he T ro ub le with Mixe d Ma trix Me mb ra ne s CO 2 N 2 CO 2 N 2 “T rue ” MMM Pa rtic le T ra nspo rt Bypa ss

I nte rfa c ia lly-Co ntro lle d E nve lo pe (I CE ) Me mb ra ne s I f yo u c a n’ t b e a t ‘ e m, jo in ‘ e m! CO 2 N 2 • Ma ke s use o f e nve lo pme nt e ffe c ts • Diffusio n phe no me na de te rmine d b y inte ra c tio ns with the pa rtic le a nd po lyme r surfa c e • Adva nc e d po lyme rs a llo w a n e xc e lle nt sta rting po int

Me mb ra ne F a b ric a tio n a nd Optimiza tio n Na no -pa rtic le Me mb ra ne F ilm Se le c tio n F a b ric a tio n Na no -pa rtic le Mo dific a tio n

Pe rfo rma nc e T e sting I so c ho ric I so b a ric Syste m Syste m

Wha t is g re a t a b o ut po lypho spha ze ne s? • Co mpa re d to c la ssic a l o rg a nic po lyme rs, the ino rg a nic b a c kb o ne pro vide s sta b ility to o xida tio n a nd pho to lysis, a nd re sista nc e to ma ny re a g e nts tha t wo uld de c o mpo se pe tro c he mic a l-b a se d po lyme rs. T he b a c kb o ne a lso g ive s rise to po lyme rs with lo w g la ss tra nsitio n te mpe ra ture s. • T he ma c ro mo le c ula r sub stitutio n a ppro a c h a llo ws the synthe sis o f hundre ds o f diffe re nt po lyme rs with a wide ra ng e o f pro pe rtie s ma ny o f whic h c a nno t b e g e ne ra te d fro m c o nve ntio na l po lyme rs. • T he se spe c ia l pro pe rtie s inc lude c o ntro l o f me mb ra ne c ha ra c te ristic s, suc h a s hig h tra nsmissio n o f g a se s suc h a s CO 2 , c o ntro lle d g la ss tra nsitio n a nd me lting te mpe ra ture s, a nd sta b ility to ma ny c he mic a ls. • Pro pe rty tuning is a c c o mplishe d b y c ha ng ing a ny o f 250 diffe re nt side g ro ups a nd the ir ra tio s within the po lyme r. • F urthe r c ha ng e s a re po ssib le b y surfa c e re a c tio ns, a nd via c o mpo site s suc h a s inte rpe ne tra ting po lyme r ne two rks. Also b lo c k c o po lyme rs a re a c c e ssib le . .

T he Ma c ro mo le c ula r Sub stitutio n Me tho d Mor e than 250 diffe r e nt side gr oups use d e ithe r alone or in c ombinations to give se ve r al hundr e d diffe r e nt polyme r s made by this me thod at Pe nn State . E ac h Diffe r e nt Side gr oup ar r ange me nts give s a polyme r with diffe r e nt pr ope r tie s and pote ntial use s.

Ca rrying Out Re a c tio ns o n a Hig h Mo le c ula r We ig ht Po lyme r Pre se nts So me Uniq ue Cha lle ng e s a nd Oppo rtunitie s

E xa mple s o f Po lypho spha ze ne Me mb ra ne s [NP(OCH 2 CF 2 CF 2 CF 2 CF 2 H) 2 ] n [NP(OCH 2 CF 3 ) 2 ] n

T a sks fo r Budg e t Pe rio d 1 (2016) • T a sk 2: Co mpute r Simula tio n o f Hyb rid Pro c e ss • 2.1: Simula tio n o f Me mb ra ne Syste m • 2.2: Simula tio n o f Ab so rptio n/ Air Stripping Syste m • 2.3: Simula tio n o f He a t Pump Cyc le • 2.4: Optimiza tio n o f Hyb rid Pro c e ss • T a sk 3: Ge ne ra tio n 0 I CE Me mb ra ne De ve lo pme nt • 3.1: Po lypho spha ze ne Synthe sis a nd Cha ra c te riza tio n • 3.2: De sig n a nd Co nstruc tio n o f I so c ho ric Me mb ra ne Syste m • 3.3: Ge ne ra tio n 0 I CE Me mb ra ne Pe rfo rma nc e T e sting • 3.4: Na no -fille r Pa rtic le Se le c tio n • T a sk 4: Mo dific a tio n, I nsta lla tio n, a nd T e sting o f Ab so rptio n Co lumn • 4.1: Mo dific a tio n o f Ab so rptio n Co lumn • 4.2: I nsta lla tio n o f Ab so rptio n Co lumn • 4.3: Pa ra me tric T e sting o f Ab so rptio n Co lumn

T a sks fo r Budg e t Pe rio d 2 (2017) • T a sk 5: Ge ne ra tio n 1 I CE Me mb ra ne De ve lo pme nt • 5.1: Po lypho spha ze ne Optimiza tio n a nd Cha ra c te riza tio n • 5.2: F a b ric a tio n o f Ge ne ra tio n 1 I CE Me mb ra ne • 5.3: Ge ne ra tio n 1 I CE Me mb ra ne Pe rfo rma nc e T e sting • 5.4: De sig n a nd Co nstruc tio n o f Mixe d Ga s Me mb ra ne T e sting Syste m • T a sk 6: Mo dific a tio n, I nsta lla tio n, a nd T e sting o f Air Strippe r • 6.1: Mo dific a tio n o f Air Strippe r • 6.2: I nsta lla tio n o f Air Strippe r • 6.3: Pa ra me tric T e sting o f Air Strippe r

T a sks fo r Budg e t Pe rio d 3 (2018) • T a sk 7: I CE Me mb ra ne Sc a le -up a nd Simula te d F lue Ga s T e sting • 7.1: Po lypho spha ze ne Sc a le -up a nd Cha ra c te riza tio n • 7.2: F a b ric a tio n o f Optimize d1 I CE Me mb ra ne • 5.3: Simula te d F lue Ga s T e sting • T a sk 8: I nitia l T e c hnic a l a nd E c o no mic F e a sib ility Study • 8.1: Syste m Pe rfo rma nc e Mo de ling • 8.2: E c o no mic Ana lysis • 8.3: Se nsitivity Ana lysis

Sc he dule

Budg e t Budg e t Pe riod 1 Budg e t Pe riod 2 Budg e t Pe riod 3 T ota l Proje c t 10/ 01/ 15- 09/ 30/ 16 10/ 01/ 16- 09/ 30/ 17 10/ 01/ 17- 09/ 30/ 18 NE T L Sha re Cost Sha re NE T L Sha re Cost Sha re NE T L Sha re Cost Sha re NE T L Sha re Cost Sha re $337,781 $84,445 $330,789 $82,697 $268,345 $67,086 $936,914 $234,228 L IS $160,000 $40,000 $160,000 $40,000 $160,000 $40,000 $480,000 $120,000 Pe nn Sta te $276,646 $69,162 $166,051 $41,513 $138,418 $34,605 $581,116 $145,280 CCS $774,427 $193,607 $656,840 $164,210 $566,763 $141,691 $1,998,030 $499,508 T ota l Cost Sha re 80% 20% 80% 20% 80% 20% 80% 20%

T e c hnic a l Risks • Po lypho spha ze ne Pe rfo rma nc e I nsuffic ie nt • I nsuffic ie nt Co ntro l o f I nte rfa c ia l E nve lo pe • L a c k o f Re pro duc ib ility o f Me mb ra ne Re sults Be c a use o f Mino r Diffe re nc e s in F a b ric a tio n Pro c e dure • E ne rg y Co nsumptio n in He a t Pump Syste m T o o Hig h • Ca pita l Co st fo r So lve nt Syste m T o o Hig h

Re so urc e Risks • I na b ility to L o c a te Qua lifie d Sta ff • L o ss o f Se nio r T e a m Me mb e r • L a c k o f Ana lytic a l Re so urc e s Ma na g e me nt Risks • Pro b le ms with I nitia ting Wo rk Pro c e sse s fo r Ne w Co mpa ny • Co lla b o ra tio n Pro b le ms Amo ng Org a niza tio ns

I P Risks • I P Ag re e me nts No t Re a c he d with Sub c o ntra c to rs • Othe rs Ma ke Use o f Pro c e ss I nno va tio ns Be c a use o f L a c k o f I P Pro te c tio n • Pa te nts No t I ssue d fo r Po lyme rs • I CE Me mb ra ne F a b ric a tio n Me tho ds No t Pa te nta b le