TiZir – Fra kull til hydrogen H 2 symposium – Tyssedal 6 th of February 2018 Stian Seim www.tizir.co.uk
TiZir Titanium & Iron production process Raw material Arc furnace Product Prereduction Customer High TiO 2 pigment Ilmenite titania slag Ti metal Rotary Electric arc kiln furnace Casting High purity Coal pig iron goods 06 February 2018 2
CO 2 emissions (Norway) 06 February 2018 3
CO 2 emissions (TiZir Titanium & Iron) Kilde: Miljødepartementet TiZir Titanium & Iron emits 3 % of «Norsk Industri og Bergverk» GHG emissions. Emissions have decreased by 10 % between 2007 – 2014. Decrease mainly due to technical development. 06 February 2018 4
Process industry challenge Energy generation: 𝐷 + 𝑃 2 = 𝐷𝑃 2 + 𝐹𝑜𝑓𝑠𝑧 Change to renewable sources Material reduction: 𝐷 + 2𝑁𝑓𝑃 + 𝐹𝑜𝑓𝑠𝑧 = 𝑁𝑓 + 𝐷𝑃 2 Change chemical reactant 06 February 2018 5
Process industry challenge Not an energy carrier question Change of chemical reactants Development of new processes Technology development Raw material development 06 February 2018 6
TiZir Titanium & Iron solution Ilmenite reduction with carbon 2𝐺𝑓𝑈𝑗𝑃 3 + 𝐷 → 2𝐺𝑓 + 2𝑈𝑗𝑃 2 + 𝐷𝑃 2 Ilmenite reduction with hydrogen 𝐺𝑓𝑈𝑗𝑃 3 + 𝐼 2 → 𝐺𝑓 + 𝑈𝑗𝑃 2 + 𝐼 2 𝑃 06 February 2018 7
Hydrogen benefits Stephen C. Lobo, Experimental investigations and modelling of solid-state ilmenite reduction with hydrogen and carbon monoxide, Ph.D. thesis, NTNU, 2015 06 February 2018 8
Stage 1 – 2015 Upgrade of the arc furnace Enabling handling of H 2 reduced material Decreased specific CO 2 emission (~10 %) Decreased specific energy consumption Improved gas cleaning system 47 % investment support from ENOVA 06 February 2018 9
TTI today Coal Ilmenite Furnace off gas (CO) Flare Rotary Kiln Pre- Smelting reduction Charging Furnace Slag & Iron 06 February 2018 10
New technology Natural Gas Ilmenite Furnace off gas (CO) SMR Plant Hydrogen Smelting Pre-Reduction Charging Charging Furnace Electrolyser Plant Slag & Iron 06 February 2018 11
Development Start in 2012 with technology screening 2013 bench scale batch testing 2014 – bench scale continuous testing 2016 – testing special issues 2016 DFS demonstration plant 2014 PFS full scale plant 2015 PhD thesis – Hydrogen reduction of ilmenite 06 February 2018 12
Risk management Risk Incentives Climate goals Norwegian Research Council Globalization Innovasjon Norge New technology ENOVA Replacing existing New market equipment opportunities Power pricing Capex 06 February 2018 13
It’s a rocky road ahead But if we don’t start we’ll never get there 06 February 2018 14
Thank you for your attention Contact: Stian Seim, PhD Research and Development Manager stian.seim@ttinorway.com 06 February 2018 15
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