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- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + - - - - - - - - - - - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + ELECTROLYTE ELECTROLYTE ELECTROLYTE ELECTROLYTE ELECTROLYTE ELECTROLYTE ELECTROLYTE • Discovered by Helmholtz in 1800s 2 on electrode surface C ~ 10 m F/cm • • Physical charge storage (not chemical) • Voltage limited--electrolyte decomposition potential • High-surface-area electrodes--large capacitances JME Slide 23
DOUBLE LAYER CAPACITOR CONCEPT + + - - + + - - v v v v v v v v v + + + + + + + + + + + + + + + + + + + + + - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + - - - - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + - - - - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + + + + + + + + - - - - - - - - - - - - - - - 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- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + + + + - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + - - - - - - - - - - - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + + + + + + + + - - - - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + + + + - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + - - - - - - - - - - - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + ELECTROLYTE ELECTROLYTE ELECTROLYTE ELECTROLYTE ELECTROLYTE ELECTROLYTE ELECTROLYTE d~1 nm • Discovered by Helmholtz in 1800s 2 on electrode surface C ~ 10 m F/cm • • Physical charge storage (not chemical) • Voltage limited--electrolyte decomposition potential • High-surface-area electrodes--large capacitances Electric Double Layer JME Slide 24
Typical Electrochemical Capacitor Construction Electrodes typically ~1500 m 2 /g ~3000 F, 2.85 V > 10 6 cycles, >2000 hr life @ 65 o C C/M > 100 F/g ~1 second response time JME Slide 25
Typical Electrochemical Capacitor Construction Electrodes typically ~1500 m 2 /g C/M > 100 F/g JME Slide 26
Typical Electrochemical Capacitor Construction Electrodes typically ~1500 m 2 /g ~3000 F, 2.85 V > 10 6 cycles, >2000 hr life @ 65 o C C/M > 100 F/g ~1 second response time JME Slide 27
Small Electrochemical Capacitor Products NEC-Tokin cap-XX Danionics PowerStor General Capacitor FastCAP Panasonic ELNA JME Slide 28
Large EC Products ELIT Maxwell Nippon Chemi-Con Eaton ESMA Ioxus LS Mtron Wima Yunasko JME Meiden Batscap JSR Micro Slide 29
EC -- Battery Comparison PROPERTY BATTERY EC Storage mechanism Chemical Physical Power limitation Reaction kinetics, Separator ionic conductivity mass transport Energy limitation Electrode mass Electrode surface area Output voltage Constant value Sloping value (SOC known precisely) Charge rate Limited by reaction Very high, same as rates discharge rate Cycle life limitations Physical stability, Side reactions chem. reversibility Life limitation Thermodynamic Side reactions stability JME Slide 30
EC -- Battery Comparison PROPERTY BATTERY EC Storage mechanism Chemical Physical Power limitation Reaction kinetics, Separator ionic conductivity mass transport Energy limitation Electrode mass Electrode surface area Output voltage Constant value Sloping value (SOC known precisely) Charge rate Limited by reaction Very high, same as rates discharge rate Cycle life limitations Physical stability, Side reactions chem. reversibility Life limitation Thermodynamic Side reactions stability JME Slide 31
EC -- Battery Comparison PROPERTY BATTERY EC Storage mechanism Chemical Physical Power limitation Reaction kinetics, Separator ionic conductivity mass transport Energy limitation Electrode mass Electrode surface area Output voltage Constant value Sloping value (SOC known precisely) Charge rate Limited by reaction Very high, same as rates discharge rate Cycle life limitations Physical stability, Side reactions chem. reversibility Life limitation Thermodynamic Side reactions stability JME Slide 32
EC -- Battery Comparison PROPERTY BATTERY EC Storage mechanism Chemical Physical Power limitation Reaction kinetics, Separator ionic conductivity mass transport Energy limitation Electrode mass Electrode surface area Output voltage Constant value Sloping value (SOC known precisely) Charge rate Limited by reaction Very high, same as rates discharge rate Cycle life limitations Physical stability, Side reactions chem. reversibility Life limitation Thermodynamic Side reactions stability JME Slide 33
EC -- Battery Comparison PROPERTY BATTERY EC Storage mechanism Chemical Physical Power limitation Reaction kinetics, Separator ionic conductivity mass transport Energy limitation Electrode mass Electrode surface area Output voltage Constant value Sloping value (SOC known precisely) Charge rate Limited by reaction Very high, same as rates discharge rate Cycle life limitations Physical stability, Side reactions chem. reversibility Life limitation Thermodynamic Side reactions stability JME Slide 34
EC -- Battery Comparison PROPERTY BATTERY EC Storage mechanism Chemical Physical Power limitation Reaction kinetics, Separator ionic conductivity mass transport Energy limitation Electrode mass Electrode surface area Output voltage Constant value Sloping value (SOC known precisely) Charge rate Limited by reaction Very high, same as rates discharge rate Cycle life limitations Physical stability, Side reactions chem. reversibility Life limitation Thermodynamic Side reactions stability JME Slide 35
Energy Storage Technology Comparison Charge/ Specific STORAGE Cycle Life COST discharge Energy TECHNOLOGY (80% DOD) ($/kWh) time (s) (Wh/kg) 2,000,000 1,000,000 20,000 1,000 Lead Acid 10 +4 >10 +2 30 100 Battery JME Slide 36
Energy Storage Technology Comparison Charge/ Specific STORAGE Cycle Life COST discharge Energy TECHNOLOGY (80% DOD) ($/kWh) time (s) (Wh/kg) 2,000,000 1,000,000 20,000 10 +2 >10 +3 Li-ion Battery 100 1,000 Lead Acid 10 +4 >10 +2 30 100 Battery JME Slide 37
Energy Storage Technology Comparison Charge/ Specific STORAGE Cycle Life COST discharge Energy TECHNOLOGY (80% DOD) ($/kWh) time (s) (Wh/kg) 2,000,000 1,000,000 Electrochemical >10 +6 1 5 20,000 Capacitor (EC) 10 +2 >10 +3 Li-ion Battery 100 1,000 Lead Acid 10 +4 >10 +2 30 100 Battery JME Slide 38
Energy Storage Technology Comparison Charge/ Specific STORAGE Cycle Life COST discharge Energy TECHNOLOGY (80% DOD) ($/kWh) time (s) (Wh/kg) 2,000,000 Electrolytic 10 -4 >10 +10 0.05 1,000,000 Capacitor Electrochemical >10 +6 1 5 20,000 Capacitor (EC) 10 +2 >10 +3 Li-ion Battery 100 1,000 Lead Acid 10 +4 >10 +2 30 100 Battery JME Slide 39
Energy Storage Technology Comparison Charge/ Specific STORAGE Cycle Life COST discharge Energy TECHNOLOGY (80% DOD) ($/kWh) time (s) (Wh/kg) Electrostatic 10 -9 >10 +15 0.001 2,000,000 Capacitor Electrolytic 10 -4 >10 +10 0.05 1,000,000 Capacitor Electrochemical >10 +6 1 5 20,000 Capacitor (EC) 10 +2 >10 +3 Li-ion Battery 100 1,000 Lead Acid 10 +4 >10 +2 30 100 Battery JME Slide 40
Energy Storage Technology Comparison Charge/ Specific STORAGE Cycle Life COST discharge Energy TECHNOLOGY (80% DOD) ($/kWh) time (s) (Wh/kg) Electrostatic 10 -9 >10 +15 0.001 2,000,000 Capacitor Electrolytic 10 -4 >10 +10 0.05 1,000,000 Capacitor Electrochemical >10 +6 1 5 20,000 Capacitor (EC) 10 +2 >10 +3 Li-ion Battery 100 1,000 Lead Acid 10 +4 >10 +2 30 100 Battery JME Slide 41
Capacitor--Battery Charging Comparison 3000 F capacitor and 12 Ah Li-ion battery Regenerative Energy Measurement JME Slide 42
Capacitor--Battery Charging Comparison 1000 1000 3000 F capacitor and 12 Ah Li-ion battery battery battery Specific Energy (kJ/kg) Specific Energy (kJ/kg) 100 100 15 times Regenerative Energy Measurement captured captured capacitor capacitor 10 10 stored stored Equal 1 1 1 1 10 10 100 100 1000 1000 10000 10000 Charging time (s) Charging time (s) 10 10 0 0 capacitor capacitor 80 80 battery battery Efficiency (%) Efficiency (%) 60 60 40 40 20 20 0 0 1 1 10 10 100 100 1000 1000 10000 10000 Tim Tim e(s) e(s) Charging time (s) JME Slide 43
Capacitor--Battery Charging Comparison 1000 1000 3000 F capacitor and 12 Ah Li-ion battery battery battery Specific Energy (kJ/kg) Specific Energy (kJ/kg) 100 100 15 times Regenerative Energy Measurement captured captured capacitor capacitor 10 10 stored stored Equal 1 1 1 1 10 10 100 100 1000 1000 10000 10000 Charging time (s) Charging time (s) 10 10 0 0 capacitor capacitor 80 80 battery battery Efficiency (%) Efficiency (%) 60 60 40 40 20 20 0 0 1 1 10 10 100 100 1000 1000 10000 10000 Tim Tim e(s) e(s) Charging time (s) JME Slide 44
EC Summary • Extraordinarily high specific capacitance ~100 F/g • High energy compared with conventional capacitors • Low unit-cell voltage, ~1 to 3 V • Response time typically ~1 s • Expensive on an energy basis (compared with batteries) • Powerful compared with batteries, especially during charge • Unlimited cycle life in most application JME Slide 45
70 kJ of Stored Energy JME Slide 46
Outline - Electrochemical capacitor (EC) energy storage introduction - Energy storage technology comparisons - EC energy-conservation applications - Energy-sector applications of ECs - Storage system economic analysis - Summary JME Slide 47
: E = ½ MV 2 Energy of Motion 2000 1500 Kinetic Energy (kJ) 1000 500 0 m/s 0 5 10 15 20 25 30 mph Velocity JME Slide 48
First Large Capacitor Hybrid Vehicle (1997) 20 F, 400 V system • • ~1.6 MJ stored energy (440 Wh) NASA Report TM-113176 JME Slide 49
Battery Problems Listed: • Inadequate life • Limited current (discharge and charge) • Inaccurate measurement of SOC • Safety issues First Large Capacitor Hybrid Vehicle (1997) 20 F, 400 V system • • ~1.6 MJ stored energy (440 Wh) NASA Report TM-113176 JME Slide 50
NASA Hybrid Gas-Electric Transit Bus with EC Storage 46 second Repeating Power Profile 25 F capacitor, series resistance ~0.04 ohm (RC~1 s) Power (kW) Capacitor Brake Accelerate Voltage (V) Capacitor JME Slide 51
Crosspoint Kinetics Next Generation Electric Hybrid System with EC Storage JME Slide 52
Subway Train with Capacitor Storage JME Slide 53
Komatsu PC200-8 Hybrid Excavator with EC Storage • Electric motor turret rotation • Capacitor energy storage • Regenerative turret braking JME Slide 54
Komatsu PC200-8 Hybrid Excavator with EC Storage • Electric motor turret rotation • Capacitor energy storage • Regenerative turret braking • Introduced 2008 • Typically yields >30% fuel savings • Now selling 3 rd generation model • World-wide sales >2500 units JME Slide 55
Caterpillar 6120B H FS Hybrid Mining Shovel •1400 Tons • Bucket volume 46 to 65 m 3 (size depends on material density) • IC engine power 4500 hp (3360 kW) • Machine power 8,000 hp (using IC engine + energy storage) • 48 MJ capacitor energy storage (4700 cells each rated at 3000 F, 2.7 V) JME Slide 56
Caterpillar 6120B H FS Hybrid Mining Shovel •1400 Tons • Bucket volume 46 to 65 m 3 (size depends on material density) • IC engine power 4500 hp (3360 kW) • Machine power 8,000 hp (using IC engine + energy storage) • 48 MJ capacitor energy storage (4700 cells each rated at 3000 F, 2.7 V) • Regen energy capture during swing deceleration and boom-down movement • ~25% fuel savings achieved over non-hybrid version JME Slide 57
Energy of Location : E = MgH 2000 1500 Potential Energy (kJ) 1000 500 0 0 5 10 15 20 25 30 Height (m) JME Slide 58
Container Ship at Port Up to 7,600 40-ft containers Container mass up to 40 MT Ship load up to 157,000 MT Load can fill 35 100-car trains JME Slide 59
Hybrid Rubber Tired Gantry Crane with EC Storage 7 MJ Capacitor--Efficient Regenerative Energy Capture ~40 % Fuel Saving / Significant Emission Reduction Capacitor storage JME Source: T. Furukawa, NCC Slide 60
Hybrid Rubber Tired Gantry Crane with EC Storage RESULTS JME Source: T. Furukawa, NCC Slide 61
Outline - Electrochemical capacitor (EC) energy storage introduction - Energy storage technology comparisons - EC energy-conservation applications - Energy-sector applications of ECs - Storage system economics - Summary JME Slide 62
ECs for Wind Turbine Emergency Pitch Control JME Slide 63
ECs for Wind Turbine Emergency Pitch Control Attractive EC features • High reliability • Long operational-life • Maintenance-free • Low-temperature operation • High power performance • Safe • High cycle-life JME Slide 64
EC Voltage Compensation System JME Slide 65
EC Voltage Compensation System JME Slide 66
EC Voltage Compensation System Attractive EC features • High reliability • High power performance • Safe • Long operational-life • High cycle-life JME Slide 67
ECs for Solar Thermal Electricity Generation Ivanpah, California, USA • completed in 2013 by Brightsource • 377 MW output • three 137-meter-tall towers • 300,000 mirrors track the sun all day JME Slide 68
ECs for Solar Thermal Electricity Generation Ivanpah, California, USA • completed in 2013 by Brightsource • 377 MW output • three 137-meter-tall towers • 300,000 mirrors track the sun all day • each mirror requires electrical power • EC stored energy used for mirror control JME Slide 69
Renewable Energy Generation/Demand Exampl e Blue—wind power 30 days of data Gold—solar power JME April 2010 Red—power demand Bonneville Power Admin. (Black lines—averages) Slide 70
JME Slide 71
Time Shifting—Day/Night Storage 24 hours NO STORAGE JME Slide 72
Time Shifting—Day/Night Storage 24 hours 24 hours NO STORAGE WITH STORAGE JME Slide 73
Time Shifting—Day/Night Storage 24 hours 24 hours NO STORAGE WITH STORAGE 20 years at 1 cycle per day, five days per week requires ~5000 cycles JME Slide 74
Day-Night Energy Storage Systems • Used with the electric power grid JME Slide 75
Day-Night Energy Storage Systems • Used with the electric power grid • Mass and volume of storage--low direct importance (stationary) JME Slide 76
Day-Night Energy Storage Systems • Used with the electric power grid • Mass and volume of storage--low direct importance (stationary) • Often designed to operate at low rate (~5 h charge/discharge) JME Slide 77
Day-Night Energy Storage Systems • Used with the electric power grid • Mass and volume of storage--low direct importance (stationary) • Often designed to operate at low rate (~5 h charge/discharge) • Typically need to operate for 15 to 20 years JME Slide 78
Day-Night Energy Storage Systems • Used with the electric power grid • Mass and volume of storage--low direct importance (stationary) • Often designed to operate at low rate (~5 h charge/discharge) • Typically need to operate for 15 to 20 years • Must compete with new-power generation JME Slide 79
Day-Night Energy Storage Systems • Used with the electric power grid • Mass and volume of storage--low direct importance (stationary) • Often designed to operate at low rate (~5 h charge/discharge) • Typically need to operate for 15 to 20 years • Must compete with new-power generation • Important metric—cost of storing energy ($/kWh) JME Slide 80
Day-Night Energy Storage Systems • Used with the electric power grid • Mass and volume of storage--low direct importance (stationary) • Often designed to operate at low rate (~5 h charge/discharge) • Typically need to operate for 15 to 20 years • Must compete with new-power generation • Important metric—cost of storing energy ($/kWh) World Energy Storage World Total: 126,000 MW (2010) World Total: 126,000 MW (2010) 2010 JME Source- California Energy Storage Alliance. “Energy Storage: Bolstering California’s Economy with AB 2514” page 3. Source- California Energy Storage Alliance. “Energy Storage: Bolstering California’s Economy with AB 2514” page 3. Source- California Energy Storage Alliance. “Energy Storage: Bolstering California’s Economy with AB 2514” page 3. Slide 81
Pumped Hydroelectric Storage Schematic JME Slide 82
Pumped Hydroelectric Energy Storage JME Source: Wikipedia accessed 1-11-2018 Slide 83
Tumut 3 Power Station 1 st pumped hydroelectric station in New South Wales JME Slide 84
ENERGY STORAGE COMPONENTS Battery Capacitor Secondary Primary electrostatic (rechargeable) electrolytic electrochemical Lead Li ion NiCd NMH acid symmetric asymmetric Aqueous Aqueous Organic Organic electrolyte electrolyte electrolyte electrolyte Original EC Lithium-ion Most popular today capacitor “LIC” Potential for bulk storage JME Slide 85
ENERGY STORAGE COMPONENTS Battery Capacitor Secondary Primary electrostatic (rechargeable) electrolytic electrochemical Lead Li ion NiCd NMH acid asymmetric Aqueous electrolyte Potential for bulk storage JME Slide 86
Typical EC Cell Cross-section SYMMETRIC EC Both electrodes same materials (usually activated carbon) and each about same thickness JME Slide 87
Typical EC Cell Cross-section SYMMETRIC EC Both electrodes same materials (usually activated carbon) and each about same thickness ASYMMETRIC EC Positive and negative electrodes are different materials with capacity of one electrode much greater than other JME Slide 88
Asymmetric Electrochemical Capacitors Double layer Double layer Double layer Faradaic _ _ _ _ + + + + + electrolyte electrolyte electrolyte + electrolyte + + - - + Q Q + Symmetric design Asymmetric design JME Slide 89
Asymmetric Electrochemical Capacitors Double layer Double layer Double layer Faradaic _ _ _ _ + + + + + electrolyte electrolyte electrolyte + electrolyte + + - - + Q Q + Symmetric design Asymmetric design JME Slide 90
Asymmetric Electrochemical Capacitors Double layer Double layer Double layer Faradaic _ _ _ _ + + + + + electrolyte electrolyte electrolyte + electrolyte + + - - + Q Q + Symmetric design Asymmetric design Asymmetric ECs • Lower cost than symmetric design • Asymmetry ratio establishes cycle life • Low embedded energy • Safe--locate anywhere (e.g. building basement) • Size scalable • Low projected energy storage costs (<$0.07/kWh) JME Slide 91
Asymmetric Electrochemical Capacitor JME Slide 92
Early Capacitor Powered Electric Bus and Truck ~1995 Gazel Truck ~1993 ELTON Bus 30 MJ ELTON NiOOH/KOH/C EC, 70 km/hr 30 MJ, 190 V, NiOOH/KOH/C storage system 30 km range, 15 minute charge 15 km range, 25 km/hr, 15 minute charge factory to warehouse operation circle route operation in large Moscow park JME Slide 93
Characteristics of Asymmetric ECs (aqueous electrolyte) + Tolerant to over-voltage conditions + Voltage self-balance in series strings + Electrode drying unnecessary + Low-cost packaging possible since water not contaminant + Very low self-discharge rate is possible + High electrolyte salt concentration possible JME Slide 94
Characteristics of Asymmetric ECs (aqueous electrolyte) + Tolerant to over-voltage conditions + Voltage self-balance in series strings + Electrode drying unnecessary + Low-cost packaging possible since water not contaminant + Very low self-discharge rate is possible + High electrolyte salt concentration possible - Longer response times (lower power) - Cycle life lower than symmetric EC—set by asymmetry ratio - Cannot be discharged to and held at 0 V JME Slide 95
ELTON Pb/C Asymmetric Electrochemical Capacitor for the Electric Grid Charge Charge Charge PbSO 4 + 2H 2 O ? PbO 2 + H 2 SO 4 + PbSO 4 + 2H 2 O ? PbO 2 + H 2 SO 4 + PbSO 4 + 2H 2 O ? PbO 2 + H 2 SO 4 + 2H + + 2e - 2H + + 2e - 2H + + 2e - Discharge Discharge Discharge C neg up to 1600 F/g due to the small size of H + and its low-level C neg up to 1600 F/g due to the small size of H + and its low-level C neg up to 1600 F/g due to the small size of H + and its low-level interaction with activated carbon structure interaction with activated carbon structure interaction with activated carbon structure JME <$0.10/kWh projected storage cost Slide 96
ELTON Pb/C Asymmetric Electrochemical Capacitor for the Electric Grid Sample #1 Sample #1 Sample #1 Sample #2 Sample #2 Sample #2 Pilot prototype Pilot prototype ELTON HES-340F1 ELTON HES-340F1 C/5 discharge, 25 o C, 100% DOD Conditions: full cell test, ambient temperature (+25 o C), 100% DOD. Conditions: full cell test, ambient temperature (+25 o C), 100% DOD. JME Slide 97
Fill Decommissioned Power Plants with Capacitors JME Slide 98
Fill Decommissioned Power Plants with Capacitors Note: • Empty building • Transmission switchyards often intact • Extends life of capital investment • Promotes removal of inefficient plants • Permitting should not be difficult JME Slide 99
Fill Decommissioned Power Plants with Capacitors Note: • Empty building • Transmission switchyards often intact • Extends life of capital investment • Promotes removal of inefficient plants • Permitting should not be difficult 50m x 100m x 20m = 100,000 m 3 JME Slide 100
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