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Explosive Condensation in a One-dimensional Particle System Bartek Waclaw and Martin R. Evans SUPA, School of Physics and Astronomy, University of Edinburgh, U.K. May 21, 2014 Other Collaborators: S. N. Majumdar (LPTMS, Paris), R. K. P. Zia


  1. Explosive Condensation in a One-dimensional Particle System Bartek Waclaw and Martin R. Evans SUPA, School of Physics and Astronomy, University of Edinburgh, U.K. May 21, 2014 Other Collaborators: S. N. Majumdar (LPTMS, Paris), R. K. P. Zia (Virginia Tech, USA) M. R. Evans Explosive Condensation in a 1d Particle System

  2. Plan Plan: I Real Space Condensation Zero Range Process Factorised Steady State ( FSS ) Condensation and large deviations of sums of random variables M. R. Evans Explosive Condensation in a 1d Particle System

  3. Plan Plan: I Real Space Condensation Zero Range Process Factorised Steady State ( FSS ) Condensation and large deviations of sums of random variables II Explosive Condensation ‘Misanthrope’ process Dynamics of condensation M. R. Evans Explosive Condensation in a 1d Particle System

  4. Plan Plan: I Real Space Condensation Zero Range Process Factorised Steady State ( FSS ) Condensation and large deviations of sums of random variables II Explosive Condensation ‘Misanthrope’ process Dynamics of condensation References: T Hanney and M.R. Evans, J. Phys. A (2005) M. R. Evans, S. N. Majumdar and R. K. P. Zia J. Stat. Phys. (2006) B. Waclaw and M. R. Evans, Phys. Rev. Lett. 108, 070601 (2012), J. Phys. A (2014) M. R. Evans Explosive Condensation in a 1d Particle System

  5. Zero-Range Process i a) u(3) u(2) u(1) Site: 1 2 3 4 5 b) u(3) u(1) u(2) Particle: 1 2 3 4 5 a) “balls-in-boxes” picture b) “Exclusion Process” picture M. R. Evans Explosive Condensation in a 1d Particle System

  6. Zero-Range Process i a) u(3) u(2) u(1) Site: 1 2 3 4 5 b) u(3) u(1) u(2) Particle: 1 2 3 4 5 a) “balls-in-boxes” picture b) “Exclusion Process” picture Generator � f ( η i i +1 ) − f ( η ) � � L f ( η ) = u ( η i ) i M. R. Evans Explosive Condensation in a 1d Particle System

  7. Motivation for ZRP Specific physical systems map onto ZRP e.g. polymer dynamics, sandpile dynamics, traffic flow Effective description of dynamics involving exchange between domains e.g. phase separation dynamics Factorised Steady State (system of L sites and N particles) 1 � P( m 1 ..... m L ) = f ( m 1 ) . . . f ( m L ) δ ( m i − N ) Z N , L i where the single-site weight f ( m ) m 1 � f ( m ) = u ( n ) n =1 M. R. Evans Explosive Condensation in a 1d Particle System

  8. Factorised Stationary States 1 � P( m 1 ..... m L ) = f ( m 1 ) . . . f ( m L ) δ ( m i − N ) Z N , L i where the single-site weight f ( m ) m 1 � f ( m ) = u ( n ) n =1 Normalization (Nonequilibrium partition function) ∞ � � Z N , L = f ( m 1 ) . . . f ( m L ) δ ( m j − N ) { m i =0 } j Single-site mass distribution (Marginal distribution) p ( m ) = f ( m ) Z N − m , L − 1 Z N , L M. R. Evans Explosive Condensation in a 1d Particle System

  9. Real Space Condensation Snapshot of ZRP u ( m ) = 1 + 3 m above critical density 1000 800 600 Occupation 400 200 0 0 100 200 300 400 500 600 700 800 900 1000 Lattice site M. R. Evans Explosive Condensation in a 1d Particle System

  10. Real Space Condensation Single-site mass distribution in ZRP u ( m ) = 1 + 5 m 0.001 1e-06 ln p(n) 1e-09 1e-12 1 10 100 1000 10000 ln n below critical density ( ρ = N L ) above critical density (note condensate bump p bump ) M. R. Evans Explosive Condensation in a 1d Particle System

  11. Real Space Condensation p gc ( m ) = Az m f ( m ) Grand Canonical Ensemble: z < 1 z is fugacity ∞ N � Constraint: mp gc ( m ) = ρ ≡ lim L L , N →∞ m =0 i.e. density ρ ( z ) as function of z M. R. Evans Explosive Condensation in a 1d Particle System

  12. Real Space Condensation p gc ( m ) = Az m f ( m ) Grand Canonical Ensemble: z < 1 z is fugacity ∞ N � Constraint: mp gc ( m ) = ρ ≡ lim L L , N →∞ m =0 i.e. density ρ ( z ) as function of z If u ( m ) = 1 + γ f ( m ) ∼ m − γ m ⇒ M. R. Evans Explosive Condensation in a 1d Particle System

  13. Real Space Condensation p gc ( m ) = Az m f ( m ) Grand Canonical Ensemble: z < 1 z is fugacity ∞ N � Constraint: mp gc ( m ) = ρ ≡ lim L L , N →∞ m =0 i.e. density ρ ( z ) as function of z If u ( m ) = 1 + γ f ( m ) ∼ m − γ m ⇒ Then z → z ∗ = 1 gives the max allowed value of density ρ max ρ max → ∞ if γ ≤ 2 ρ max → ρ c < ∞ if γ > 2 M. R. Evans Explosive Condensation in a 1d Particle System

  14. Real Space Condensation p gc ( m ) = Az m f ( m ) Grand Canonical Ensemble: z < 1 z is fugacity ∞ N � Constraint: mp gc ( m ) = ρ ≡ lim L L , N →∞ m =0 i.e. density ρ ( z ) as function of z If u ( m ) = 1 + γ f ( m ) ∼ m − γ m ⇒ Then z → z ∗ = 1 gives the max allowed value of density ρ max ρ max → ∞ if γ ≤ 2 ρ max → ρ c < ∞ if γ > 2 Thus for γ > 2 we have condensation if ρ > ρ c In condensed phase critical fluid p ∗ gc ( m ) coexists with condensate p bump ( m ) M. R. Evans Explosive Condensation in a 1d Particle System

  15. Nature of the Condensate: a large deviation effect Canonical partition function : (computed in EMZ 2006)   ∞ L L � � � Z N , L = f ( m i ) δ m j − N   { m i =0 } i j M. R. Evans Explosive Condensation in a 1d Particle System

  16. Nature of the Condensate: a large deviation effect Canonical partition function : (computed in EMZ 2006)   ∞ L L � � � Z N , L = f ( m i ) δ m j − N   { m i =0 } i j ∞ � w.l.o.g. let f ( m ) = 1 then m i =0 Z N , L = prob. that sum of L +ve iidrvs with distribution f ( m ) is equal to N M. R. Evans Explosive Condensation in a 1d Particle System

  17. Nature of the Condensate: a large deviation effect Canonical partition function : (computed in EMZ 2006)   ∞ L L � � � Z N , L = f ( m i ) δ m j − N   { m i =0 } i j ∞ � w.l.o.g. let f ( m ) = 1 then m i =0 Z N , L = prob. that sum of L +ve iidrvs with distribution f ( m ) is equal to N Condensate shows up in a large deviation ∞ � of a sum of random variables when N ≫ µ 1 L with m f ( m ) ≡ µ 1 < ∞ . m =0 The event that � L i =1 m i = N is most likely realised by 1 of m i being O ( L ) and the rest being O (1) M. R. Evans Explosive Condensation in a 1d Particle System

  18. Results for condensate bump scaling laws 3 > γ > 2 p cond ≃ 1 1 z = ( m − M ex ) L 1 / ( γ − 1) V γ ( z ) L 1 / ( γ − 1) L � i ∞ ds 2 π i exp( − zs + A Γ(1 − γ ) s γ − 1 ) V γ = − i ∞ strongly asymmetric γ > 3 exp( − z 2 p cond ≃ 1 1 z = ( m − M ex ) √ 2∆ 2 ) L 1 / 2 L 2 π ∆ 2 L gaussian p cond ( m ) d m = 1 � N.B. in all cases L . For rigorous work see also Grosskinsky, Schutz, Spohn JSP 2003, Ferrari, Landim, Sisko JSP 2007, Armendariz and Loulakis PTRF 2009, Beltran and Landim 2012 M. R. Evans Explosive Condensation in a 1d Particle System

  19. Physical Systems with Real-space Condensation: • Traffic and Granular flow (O’Loan, Evans, Cates, 1998) • Cluster Aggregation and Fragmentation (Majumdar et al 1998) • Granular clustering (van der Meer et al, 2000) • Phase separation in driven systems (Kafri et al, 2002). • Socio-economic contexts: company formation, city formation, wealth condensation etc. (Burda et al, 2002) • Networks (Dorogovstev & Mendes, 2003,....) • . . . M. R. Evans Explosive Condensation in a 1d Particle System

  20. Open questions • Can one analyse condensation beyond zero-range interactions? (pair-factorised states - Evans, Hanney Majumdar 2006) • Can one have a moving condensate that maintains its structure? (non-Markovian ZRP, Hirschberg, Mukamel, Schutz 2009), (tail dynamics, Whitehouse, Blythe, Evans 2014), • Condensation induced by several constraints e.g. mean and variance of mass, momentum and energy etc (Szavits-Nossan, Evans, Majumdar 2014 ) M. R. Evans Explosive Condensation in a 1d Particle System

  21. II Explosive Condensation Consider Generalisation of ZRP to dependence on target site. u ( m , n ) is rate of hopping of particle from departure site containing m to target site containing n particles sometimes called ‘misanthrope process’ (Cocozza-Thivent 1985) Generator � f ( η i i +1 ) − f ( η ) � � L f ( η ) = u ( η i , η i +1 ) i M. R. Evans Explosive Condensation in a 1d Particle System

  22. II Explosive Condensation Consider Generalisation of ZRP to dependence on target site. u ( m , n ) is rate of hopping of particle from departure site containing m to target site containing n particles sometimes called ‘misanthrope process’ (Cocozza-Thivent 1985) Generator � f ( η i i +1 ) − f ( η ) � � L f ( η ) = u ( η i , η i +1 ) i We still have factorised stationary state if u ( m , n ) satisfy : u (1 , n ) u ( m , 0) u ( m , n ) = u ( n + 1 , m − 1) u ( n + 1 , 0) u (1 , m − 1) u ( m , n ) − u ( n , m ) = u ( m , 0) − u ( n , 0) and the single-site weight becomes m u (1 , k − 1) � f ( m ) = Az m u ( k , 0) k =1 M. R. Evans Explosive Condensation in a 1d Particle System

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