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Modeling and Simulating Vortex Pinning and Transport Currents for High Temperature Superconductors Chad Sockwell Florida State University kcs12j@my.fsu.edu October 31, 2016 Chad Sockwell (FSU) Modeling SC October 31, 2016 1 / 82 Outline


  1. Modeling and Simulating Vortex Pinning and Transport Currents for High Temperature Superconductors Chad Sockwell Florida State University kcs12j@my.fsu.edu October 31, 2016 Chad Sockwell (FSU) Modeling SC October 31, 2016 1 / 82

  2. Outline Background and Motivation Superconductivity Applications High Temperature Superconductors (HTS) Vortex Pinning Ginzburg-Landau Model Basics Variants Modeling HTS Two-Band Model and Magnesium Diboride Modeling Normal Inclusions in MgB 2 Simulations Results Computational Issues Larger Domains Parallelization Decoupling Chad Sockwell (FSU) Modeling SC October 31, 2016 2 / 82

  3. Superconductivity and Motivation Chad Sockwell (FSU) Modeling SC October 31, 2016 3 / 82

  4. What is Superconductivity? Two Hallmark Properties: 1. Zero Electrical Resistance 2. The Meissner Effect The first property was discovered by Onnes in 1911. Only occurs below critical temperature T c . Normal Metal Vs. Superconductor: Chad Sockwell (FSU) Modeling SC October 31, 2016 4 / 82

  5. How does this Occur Below T c the electrons form pairs (top). Movement is orderly. No waste heat! Above T c things break down (bottom). Chad Sockwell (FSU) Modeling SC October 31, 2016 5 / 82

  6. The Meissner Effect Occurs when a superconductor (SC) is in a magnetic field. A resistance free current ( super current ) is induced. The current prevents penetration. This persists until the field reaches a critical strength H c . Magnetic Field Penetration = NO Superconductivity. Chad Sockwell (FSU) Modeling SC October 31, 2016 6 / 82

  7. Type I and Type II Type I SC are not penetrated at all (Meissner Effect) (top right). Type II SC are only penetrated by tubes of magnetic flux (Vortices) (bottom). Two critical H values, H c 1 and H c 2 . Vortex state: H c 1 < H < H c 2 . Figure : Normal and Type I (top). Type II (bottom) Chad Sockwell (FSU) Modeling SC October 31, 2016 7 / 82

  8. Why You Should Care: Applications Possible Superconducting Technology: Efficient Current Carriers MRI Powerful Magnets (by Efficient Mag Lev magnetization) Chad Sockwell (FSU) Modeling SC October 31, 2016 8 / 82

  9. The Catch There is no free lunch. T c is close to 0 K for most metals. Liquid helium is expensive. This rules out many applications such as power wires. Thankfully recent discoveries have overcome this. Chad Sockwell (FSU) Modeling SC October 31, 2016 9 / 82

  10. High Temperature Superconductors (HTS) New materials have revitalized superconductivity. Higher T c values allow the use of liquid N or O coolants. Magnesium Diboride (MgB 2 ) is cheap and ductile ( T c = 39 K or -234 ◦ C). HgBa 2 Ca 2 Cu 3 O 8 is used in MRIs ( T c = 135 K or -138 ◦ C). Hydrogen Sulfide under 150 G. Pascals of pressure ( T c = 203 K or -70 ◦ C). Chad Sockwell (FSU) Modeling SC October 31, 2016 10 / 82

  11. High Temperature Superconductors (HTS) These materials come with new odd properties: Odd temperature dependencies in quantities. All of are Type II S.C. This complicates the modeling process. Chad Sockwell (FSU) Modeling SC October 31, 2016 11 / 82

  12. Visualizing Vortices Figure : SEM image of vortices Figure : Simulation Chad Sockwell (FSU) Modeling SC October 31, 2016 12 / 82

  13. Applied Currents So far we have T c and H c . What happens when we apply a current to a SC? Can it be carried without Resistance? Only below J c ! Chad Sockwell (FSU) Modeling SC October 31, 2016 13 / 82

  14. Why Vortex Dynamics are Important Vortices (B) and Current (J)= Flux Flow. Moving Vortices (flux flow) creates Resistance. f ˆ x = J ˆ y × B ˆ z E ˆ y = B ˆ z × u ˆ x Flux Flow induces Electric Field (E) and Voltage (V). Resistance now exists ( V I =R). Chad Sockwell (FSU) Modeling SC October 31, 2016 14 / 82

  15. Vortex Pinning Comes to the Rescue Immobilizing the Vortices Is Crucial. Non Superconducting Metal= Normal Metal= Pinning Sites. (Outlined in Black) Vortices “Stick” To impurities. Limited increase In J c . Chad Sockwell (FSU) Modeling SC October 31, 2016 15 / 82

  16. Simulations Simulations are critical to modeling new technology. No models for two-band SC and vortex pinning by impurities. Larger domains to avoid boundary effects. Chad Sockwell (FSU) Modeling SC October 31, 2016 16 / 82

  17. The Framework A model: the Ginzburg-Landau model. Modify it for HTS and vortex pinning. Specify a material and model it. Modify for large scale simulations. Chad Sockwell (FSU) Modeling SC October 31, 2016 17 / 82

  18. Ginzburg-Landau Chad Sockwell (FSU) Modeling SC October 31, 2016 18 / 82

  19. Ginzburg-Landau (GL) Theory The G-L theory (or model) describes superconductivity as a phase transition for a valid temperature range. A free energy functional is formed. Its minimum is given by the G-L equations. This is done using calculus of variations. Gauge invariance. The model is non-dimensionalized using important material parameters. Chad Sockwell (FSU) Modeling SC October 31, 2016 19 / 82

  20. Important Quantities Two variables: ψ -The complex order parameter, describes the density of superconducting electrons. A - The magnetic vector potential, ∇ × A = B . Three material parameters: λ -The penetration depth. ξ - The coherence length. κ - The G-L parameter κ = λ ξ . Type I & II Revisited: Chad Sockwell (FSU) Modeling SC October 31, 2016 20 / 82

  21. The Time Dependent G-L Model (TDGL) The solution ( ψ, A ) minimizes the free energy. CGS units (no ǫ 0 or µ 0 ). Γ( ∂ψ ∂ t ) + i κ Φ ψ + ( | ψ | 2 − (1 − T )) ψ + ( − i ξ ∇ − x 0 λ A ) 2 ψ = 0 (1) T c x 0 σ ( 1 ∂ A ∂ t + ∇ Φ)+ ∇ ( ∇· A )+ ∇×∇× A + i 2 κ ( ψ ∗ ∇ ψ − ψ ∇ ψ ∗ )+ 1 λ 2 | ψ | 2 A = ∇× H λ 2 (2) + B.C.s and I.C.s H is the applied magnetic field. Note H = B − M ; M =magnetization. σ is the normal conductivity. T is temperature. Γ is relaxation constant. x 0 is scaling factor; Φ the potential is 0 by gauge choice. Chad Sockwell (FSU) Modeling SC October 31, 2016 21 / 82

  22. Super and Normal Current Two components of the electrical current. Normal Current Density The resistive, normal current. J n = σ E = σ ( 1 ∂ A ∂ t + ∇ Φ) λ Super Current Density The resistance free super current. This is the current that gives rise to the Meissner effect. J s = − i 2 κ ( ψ ∇ ψ ∗ − ψ ∗ ∇ ψ ) − 1 λ 2 | ψ | 2 A Chad Sockwell (FSU) Modeling SC October 31, 2016 22 / 82

  23. Solving The TDGL system Non-linear, time dependent, coupled system of PDEs. FEM for space. Quadratic triangular elements. Quadrature for integrals. Adaptive backward Euler for time. Newton for non-linearities. Direct or Krylov Solver? (SUPERLU DIST at first) Chad Sockwell (FSU) Modeling SC October 31, 2016 23 / 82

  24. TDGL Simulation ψ → 0 where the material is normal (vortices or impurities). λ = 60 nm, ξ = 5 nm, (1 − T T c ) = 0 . 7, T T c =0.3, H = 1 . 5 = 1 . 5 H c , and κ = 12. Chad Sockwell (FSU) Modeling SC October 31, 2016 24 / 82

  25. TDGL Simulation Chad Sockwell (FSU) Modeling SC October 31, 2016 25 / 82

  26. G-L Variants Anisotropy Anisotropy can be modeled by assuming electrons have directional dependent masses → Effective mass model. It also creates quantities for each direction: ξ x , λ x , κ x , H x c 2 +[ . ] y Normal Inclusion Impurities (Normal Inclusion model) can be modeled as well by solving a second set of equations. This is done by setting the reduced temperature (1 − T T c ) = − 1 and removing the | ψ | 2 ψ term. Applied Current Applied currents can modeled by modifying the potential Φ. − σ ∇ Φ = J Modeling Vortex Pinning= Applied Current + Normal Inclusions. Chad Sockwell (FSU) Modeling SC October 31, 2016 26 / 82

  27. Anisotropy Anisotropy distorts the shape of vortices. λ x = 60 nm, ξ x = 5 nm, (1 − T T c ) = 0 . 7, T T c =0.3, √ 2 H x c and m y = 1 H = 1 . 5 = 1 . 5 4 m x . Chad Sockwell (FSU) Modeling SC October 31, 2016 27 / 82

  28. Anisotropy Chad Sockwell (FSU) Modeling SC October 31, 2016 28 / 82

  29. G-L Variants: Normal Inclusion Model Superconducting (Ω s ), Normal (Ω n ). Ω n Ω n Ω n Ω s Ω n Ω n Ω n Chad Sockwell (FSU) Modeling SC October 31, 2016 29 / 82

  30. Two-Band Superconductivity Chad Sockwell (FSU) Modeling SC October 31, 2016 30 / 82

  31. Two-Band Superconductivity Some HTS come with odd properties. Magnesium Diboride (MgB 2 ) ( T c = 39 K) is no exception. Anisotropic direction ab . Isotropic direction c . Upward curvature in T dependence of H c 2 . Chad Sockwell (FSU) Modeling SC October 31, 2016 31 / 82

  32. Two-Band Superconductivity Addition of second superconducting band explained behavior. Bands are “pathways”. Two-band TDGL model (2B-TDGL) → ψ 1 and ψ 2 . λ i , ξ i , κ i , H i , c 2 , T i , c Composite T c , H c 2 above each band’s value from Coupling. Peculiarity: T > T 2 , c , but T < T 1 , c and Superconductivity persists. Other HTS (Iron Pnictides) possess similar behavior. Chad Sockwell (FSU) Modeling SC October 31, 2016 32 / 82

  33. Modified 2B-TDGL (M2B-TDGL) for HTS We would like to model HTS and all their odd properties. This composite model includes: Two-band Behavior Anisotropy Applied Currents Novel Strategy for Normal Inclusion How to ensure normal behavior? Chad Sockwell (FSU) Modeling SC October 31, 2016 33 / 82

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