Development of 0.1MW- class Oxy- PC Swirl Burner with Primary O 2 Direct- injection Korea Institute of Energy Research Dae Keun Lee, Dong- Soon Noh, Kyong- Bin Choi, Dong Myung Seo, Chang- Bog Ko, Eun Kyung Lee 1 st International Oxyfuel Combustion Conference Cottbus, Germany 8 th September 2009
1st International Oxyfuel Combustion Conference Contents ► Background ► Objective ► Design Concepts of Oxy- PC Burner ► Experimental Results ► Summary 2 /25
1st International Oxyfuel Combustion Conference Background ► F G R for T control Air- PC Ai Similar T field with Air- PC les s en the load for boiler des ign. ► Amount of recycled gas Retrofit or O 2 : FGR (CO 2 ) ~ 30 : 70 new build Les s volume of CO 2 than that of N 2 O O xy- PC x Larger C p of CO 2 than N 2 ► Then, similar T field? O 2 : CO 2 ~ 30 : 70 3 /25
1st International Oxyfuel Combustion Conference Objective ► Matching conditions of temperature fields of Air- & Oxy- firing Test of Air- & Oxy- firing using single burner ► Coaxial nozzle type s wirl burner ► Mixing nozzle type s wirl burner Oxy- PC burner design parameters Test of newly designed Oxy- PC burner 4 /25
1st International Oxyfuel Combustion Conference Test Facility ► Furnace Cylindrical & horizontal 11 sampling & measuring ports Tertiary oxidant injection ports through side wall 450mm 3.2m 5 /25
1st International Oxyfuel Combustion Conference Coal ► Test coal Australian bituminous coal Coal analyses 6 /25
1st International Oxyfuel Combustion Conference Tested Burners ► Coaxial nozzle type swirl burner ► Mixing nozzle type swirl burner ► Multi- nozzle type swirl burner 7 /25
1st International Oxyfuel Combustion Conference Burner Design 1 Burner Nozzle type Air- firing Oxy- firing Coal + l + Coal + l + Prima imary y air Prima imary y O 2 2 /CO CO 2 Coal n l nozzl zle Coaxial nozzle Secon ondary burner Secon ondary Secon ondary swirl n nozzl zzle air O 2 2 /CO CO 2 ► Coaxial nozzle burner Conventional design for Air- PC firing 1 st & 2 nd O 2 diluted by CO 2 Comparison of Air- & Oxy- firings using the same burner 8 /25
1st International Oxyfuel Combustion Conference Result: Coaxial Nozzle Burner ► Temperature fields @ 0.1MW th , swirl no.=0.7 Similar downsteam but different upstream Air- PC, Oxy- PC, O 2 /CO 2 =29/71 Oxy- PC, O 2 /CO 2 =31/69 9 /25
1st International Oxyfuel Combustion Conference Result: Coaxial Nozzle Burner ► Centerline temperature Too cold @ O 2 /CO 2 =29/71 Upstream T can be increased by O 2 enrichment. But still lower than that of Air- firing by 80K. How to locally enrich O 2 in near- field? 10 /25
1st International Oxyfuel Combustion Conference Burner Design 2 Burner Nozzle type Air- firing Oxy- firing Coal + l + Coal + l + Prima imary y CO 2 Prima imary y air Coal n l nozzl zle Mixing Prima imary y O 2 Not ot u use sed Oxy n y nozzl zzle nozzle burner Secon ondary Secon ondary Secon ondary swirl n nozzl zzle O 2 2 /CO CO 2 air ► Mixing nozzle burner Design for primary O 2 direct- injection for Oxy- firing Attempt to increase the near- field temperature by local enrichment of O 2 Comparison of Air- & Oxy- firings using the same burner 11 /25
1st International Oxyfuel Combustion Conference Result: Mixing Nozzle Burner ► Centerline temperatures Much lower T than Air- firing over the whole region Maybe due to mixing retardation Then the hydrodynamic effects? Centerline temperature [ o C] 12 /25
1st International Oxyfuel Combustion Conference Result: Mixing Nozzle Burner ► Hydrodynamic effects Total gas flow rates equally sustained by power increase Similar T patterns can be obtained if hydrodynamically similar Then how to make similar hydrodynamic field? Centerline temperature [ o C] 13 /25
1st International Oxyfuel Combustion Conference Simple Estimates ► Hydrodynamic similarity ► Thermal similarity O 2 /N 2 or O 2 /N 2 or O 2 /CO 2 O 2 /CO 2 The same heating The same momentum flow rate Difficult to make field- s imilarities by Oxy- firing of Air- PC burner 14 /25
1st International Oxyfuel Combustion Conference Swirling Momentum ► Another consideration for hydrodynamic similarity Swirling momentum controls near- field flame shape. ► Two parameters to be matched with those of Air- firing Axial momentum flow rates Swirling momentum flow rates ► How to make these @ the same power cond. 15 /25
1st International Oxyfuel Combustion Conference Strategy ► Problem Smaller volume flow rate of CO 2 than that of N 2 Momentum flow rates of Oxy- firing less than those of Air- firing How to make the equal momentum flows ► Our strategy To make a smaller Oxy- burner than Air- burner to match the axial & swirling momentum flow rates @ the same heating/power condition Scale- down of coal & swirl nozzles 16 /25
1st International Oxyfuel Combustion Conference Burner Design 3 Burner Nozzle type Air- firing Oxy- firing Coaxial burner Coal + l + Coal + l + Prima imary y CO 2 Multi Prima imary y air 6 Oxy no xy nozzl zzle Prima imary y O 2 in coal n nozzl zzle nozzle burner Secon ondary Secon ondary Secon ondary swirl n nozzl zzle air O 2 2 /CO CO 2 ► Multi- nozzle burner Axial & swirling momentum matched with those of air- fired coaxial nozzle burner Primary O 2 direct- injection to enhance flame stability 17 /25
1st International Oxyfuel Combustion Conference Result: Multi Nozzle Burner ► Temperature fields @ 0.1MW th For Oxy- firing, O 2 /CO 2 =29/71 Slender flame broadened by swirl number Near- field T increases as swirl number. Coaxial nozzle burner, Air- firing, Swirl=0.7 Multi- nozzle burner, O xy- firing, Swirl=0.39 Multi- nozzle burner, O xy- firing, Swirl=0.70 Multi- nozzle burner, O xy- firing, Swirl=1.05 18 /25
1st International Oxyfuel Combustion Conference Result: Multi Nozzle Burner ► Centerline temperatures Largely increased upstream T than other two burners Difference of downstream T <30K 19 /25
1st International Oxyfuel Combustion Conference Result: Multi Nozzle Burner ► Effects of 1 st vs. 2 nd O 2 flow rates Very sensitive on 1 st /2 nd O 2 Air- PC, 0.1MW th , Swirl=0.7 2 =29/71, Swirl=0.7, 1 st O 2 /2 nd O Oxy- PC, 0.1MW th , O 2 /CO 2 =30/70 2 =29/71, Swirl=0.7, 1 st O 2 /2 nd O Oxy- PC, 0.1MW th , O 2 /CO 2 =25/75 20 /25
1st International Oxyfuel Combustion Conference Result: Multi Nozzle Burner ► Centerline temperatures Very sensitive near- field T on 1 st /2 nd O 2 Optimal condition: 25%<1 st O 2 <30% @ equal swirl no. to Air- firing coaxial burner 21 /25
1st International Oxyfuel Combustion Conference Exhaust CO 2 ► CO 2 exhaust concentration for multi nozzle burner Larger than 95% Max. of 97.9% 22 /25
1st International Oxyfuel Combustion Conference NO x Reduction ► NO x reduction by tertiary oxidant injection for multi nozzle burner Staged supply of oxidant through side wall of the furnace Reduced emission as injection position & amount No tertiary CO<30ppm injection 48mg/MJ 23 /25
1st International Oxyfuel Combustion Conference Summary ► Attempt to make a s imilar T field of O xy- firing to that of Air- firing ► Coaxial & mixing nozzle burners Difficult to make similar fields by Oxy- firing Hydrodynamic effects on T field were more important than expected. ► Multi- nozzle burner Scale- down to match the axial & swirling momentums to that of Air- firing of coaxial burner Most similar T field 2 =29/71, the equal swirl number and 25%<1 st O @ O 2 /CO 2 <30% ► Exhaus t CO 2 >95% for multi- nozzle burner NOx emis s ion<60mg/MJ by tertiary oxidant injection 24 /25
Thank you for your attention! Dae Keun Lee, Ph.D. Energy Eff. & Materials Convergence Research Division Korea Institute of Energy Research dklee@kier.re.kr
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