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IMPROVING WATER QUALITY USING ALGAE NRP, LLC Nutrient Removal Process Presented by: Sam Shepherd Chief Technical Officer Missing Link Technology phone 281-797-2501 email sshepherd@missinglinktechnology.net Algae to Energy Feeding and


  1. IMPROVING WATER QUALITY USING ALGAE NRP, LLC Nutrient Removal Process Presented by: Sam Shepherd Chief Technical Officer Missing Link Technology phone 281-797-2501 email sshepherd@missinglinktechnology.net Algae to Energy “ Feeding and Fueling the World”

  2. TECHNOLOGY Algae to Energy “Feeding and Fueling the World” SUMMARY  Biosolids Sterilization  High Temperature High Pressure Mud Motors  Algae To Energy and Food and Fertilizers and Pharmaceuticals with CO2 Capture, Potable water Generators.  Sulfur Removal from Flue Gas  Energy Recovery/Thermal Efficiency Improvement  Waste to Energy Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  3. Algae to Energy OUR ALGAE T TECHNOL NOLOG OGY “Feeding and Fueling the World” Our technologies & processes were developed directly to address the three major algae commercialization barriers; growing, harvesting and extracting algae economically on a commercial scale … MicGro HD Reactor/Process (Patent issued) GROW ALGAE  Harnesses photosynthesis to grow algae, capture CO2 and produce high-energy biomass in the High Density Reactor. The key to our design is the reactors unique ability to  First company to break the 10” algae growth barrier. bring the algae to the surface to be irradiated allowing  New bioreactor designed at four to six feet depth. for up to 6 feet versus 10 inch deep ponds and ease  Results in 5X+ improvement over nearest competitor. of retrofitted sources of CO2. Shepherd Harvester (Patent issued)  Algae harvesting process that eliminates the hydraulic transport HARVEST ALGAE requirements for harvesting algae @ 0.8% of current The keys of our process are; 1) harvesting the algae performance levels.  without pumping large volumes of the algal reactor Only harvests the mature algae which holds all the algae oil  contents, and 2) collecting the concentrated algae & Results in harvesting of oil at 3 to 5X improvement over nearest subsequent treatment to dewater and extract the competitor. EXTRACT BIOCRUDE oil/chemicals from the algae. Algaefaction (Patent issued) EXTRACT OILS  Continuous conversion of algal biomass into a “light” biocrude to be processed through existing Alginator (Patented) refineries.   Algal oil extraction technology, using We developed a proprietary catalyst that when rapid non equilibrium decompression. mixed with algae, heated and pressurized will  Utilizes energy efficiently from within produce a hydrocarbon feedstock through the the cell, and incorporates all A2E process.  technologies resulting in oil maximizing Most cost-effective catalytic process for the and extraction making it the low- conversion of algal biomass directly into cost/low-energy solution. BioCrude. … by breaking these barriers we are poised to commercially exploit the BioMass, BioOil and BioCrude markets. Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  4. Algae to Energy Markets Addressed u using ng “Feeding and Fueling the World” this T Techn hnology 1.Nutrient Remediation 2.Biomass Production (Nutraceutical / Animal Feed) 3.Algae to Crude Oil 4.Omega 3/6 Markets Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  5. Algae to Energy “Feeding and Fueling the World” PROGRA GRAM M OBJECTIVE IVES  WASTEWATER REMEDIATION USING ALGAL SYSTEMS.  THE ESTABLISHMENT OF PROFIT CENTERS BASED AROUND A2E’S CORE BUSINESS  CO 2 , N, P CAPTURE AND SEQUESTRATION Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  6. Introduction Algae to Energy “Feeding and Fueling the World” • Why remove nitrogen? – A requirement for biological phosphorus removal – High nitrate levels associated with methemoglobinemia (blue baby syndrome) – A nutrient, can lead to growth “harmful algal blooms” and hypoxic conditions • Many jurisdictions now have effluent TN limits: – EU countries – 70-80% N removal but varies – “Bubble Limits” in sensitive watersheds (e.g. Chesapeake Bay) • Canada now has effluent nitrate limits – 13 mg/L as nitrate ion after mixing – Equivalent to 2.9 mgN/L nitrate Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  7. Algae to Energy “Feeding and Fueling the World” NITROG OGEN N & P PHOSPHOR OROU OUS REMOVAL AL  Algae can metabolize sewage far more rapidly than bacterial treatment.  Treatment is more complete and more rapid since bacteriological treatment is a process of decay (generates N/P) whereas algae treatment is one of conversion of organic matter to live, healthy plant life (consumes N/P). Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  8. Algae to Energy “Feeding and Fueling the World” WAS ASTE WATER & & CO CO2 CAP CAPTURE  Conventional wastewater treatment plants account for 3 to 4 percent of all greenhouse gas emissions in the world.  A2E system is extremely efficient at capturing CO2  Large amounts of algae produced  A2E system enables a wastewater treatment plant to become carbon neutral or even carbon negative.  A2E system converts ammonia directly to plant life unlike MULTI - ALGAL SPECIES conventional systems Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  9. Algae to Energy Single Reactor Train “Feeding and Fueling the World” Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  10. Algae Growth inside Algae to Energy “Feeding and Fueling the World” a Reactor Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  11. NUTRIENT Algae to Energy “Feeding and Fueling the World” COMPARISION Algae: C : N : P = 50 : 8 : 1 Wastewater: C : N : P = 20 : 8 : 1 JUST ADD CO2 Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  12. Algae to Energy “Feeding and Fueling the World” GR GROWTH RA RATE CO COMP MPARISIONS STATE OF THE PUBLIC “DISCLOSED” TECHNOLOGY g/m 2 /day 10 – 20 ALGAE TO ENERGY TECHNOLOGY g/m 2 /day 46-188 Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  13. Fig. 1 TYPICAL NITRATE REDUCTION OVER THE 10 REACTORS Algae to Energy “Feeding and Fueling the World” Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  14. HIGHER INLET NO3 Algae to Energy “Feeding and Fueling the World” ppm Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  15. Algae to Energy PREDICTIVE MODEL “Feeding and Fueling the World” Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  16. Algae to Energy CO2 CO2-Enh Enhance anced d High “Feeding and Fueling the World” Rate P Ra Pond onds • Improved and accelerated treatment • CO2 is fixed in algal biomass • Fuel production from biomass provides greenhouse gas abatement • Energy used in WW treatment decreases • Fuel production residual becomes fertilizer Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  17. Algae to Energy “Feeding and Fueling the World” CARBO CARBON CAP CAPTURE SEAML AMLESS INTEGRATION COMBUSTION MW 16 32 44 18 3 CH4 + 6 O2 ---------> 3 CO2 + 6 H2O lbs 48 192 132 108 CAPTURE MW 44 18 62 32 3 CO2 + 5 H2O ---------> 1 ALGAE + 5 O2 lbs 132 90 62 160 Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  18. Algae to Energy “Feeding and Fueling the World” PR PRODUCT T TYPE PES Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  19. Algae to Energy “Feeding and Fueling the World” PRODUCT C T CHARACT CTERISTI TICS CS Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  20. Algae to Energy “Feeding and Fueling the World” NU NUTR TRACEUTI TICAL APPLI LICATI TIONS Confidential Company Information – Provided Under Non-Disclosure & Non-Circumvent Agreement

  21. IMPROVING WATER QUALITY USING ALGAE THANK YOU phone 281-797-2501 email sshepherd@missinglinktechnology.net Algae to Energy “ Feeding and Fueling the World”

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