Summary of 2010 Kentucky River Watershed Watch Sampling Results
What and when? Herbicides (Atrazine and 2,4-D) 23 sites in May Pathogens 168 sites in mid-July 103 sites in late July Chemicals/Nutrients/Metals 26 sites in September
Total # of KRWW Sites Sampled by Year Stabilizing at around 200? 300 248 231 250 207 202 197 189 200 176 166 # of Sites 157 155 150 115 87 100 50 0 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010
Where? ?
Field Chemistry Dissolved Oxygen – Aquatic Life Standard = 5 mg/L – 22% of stations had readings < 5 mg/L pH – Aquatic Life Standard = 6 to 9 – NO readings < 6 Temperature – None greater than Aquatic Life Std. of 31.7 ° C – Some in lakes and Ky River were close!
Herbicides Triazines Highly persistent in soil, EPA Standards only Drinking Water Standard=3.0 micrograms/L Acute Aquatic Life Standard = 350 micrograms/L Chronic Aquatic Life Standard = 12 micrograms/L 2,4-D Common herbicide to control broadleaf weeds EPA Drinking Water Standard (MCL) = 70 ppb
Atrazine detected at 4 sites in Fayette and Madison Counties:
Pathogens (E coli) Can indicate presence of other pathogens that may cause illness or infections in people. Sources include failing septic systems, straightpipes, leaking sewage lines, livestock Can reduce pathogens by maintaining septic systems, repairing sewer line leaks, increasing municipal sewerage, fencing livestock from waterways, and maintaining riparian buffers
E. coli Water Quality Standards Swimming Standard = 240 cfu/100 ml (instantaneous) Swimming Standard = 130 cfu/100ml (geometric mean of at least 5 samples in 30 days) Standards apply during Recreation Season from May 1 to October 31
Pathogen Sampling Results SYNOPTIC EVENT (mid-July) 71% (119/168) of sites exceeded instantaneous swimming standard FOLLOW-UP EVENT (late July) 80% (82/103) of sites exceeded instantaneous swimming standard
Percentage of KRWW Sites Exceeding Safe Swimming Standard for Pathogens 100 90 80 70 60 % of Synoptic 50 Sites 40 % of Follow-Up 30 Sites 20 10 0 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010
Fall Sampling Event – Nutrients, Chemistry and Metals NUTRIENTS • Nitrogen (total nitrogen, nitrate-nitrogen) • Phosphorus (total phosphorus) • Sulfur (sulfate) Lead to algal blooms, which consume oxygen as they decompose bad for aquatic life Taste and odor problems in drinking water High nitrates can cause “Blue baby” disease (or methemoglobinemia)
Adding insult to injury…
Nitrate-Nitrogen (NO 3 -N) Drinking Water Supply Std. = 10 mg/L Aquatic Life Benchmark = 3.9 mg/L No Nitrate-Nitrogen results > 10 mg/L or 3.9 mg/L Highest reading = 3.3 mg/L at K350/#1069 at Hickman Creek, Fayette County * Fewer sites sampled, mainly only new sites
Total Phosphorus Phosphorus is part of photosynthesis cycle, allowing plants to convert CO 2 to oxygen. Higher than average natural levels of phosphorus in bedrock & soils of Central Kentucky. Aquatic Life Benchmark = 0.3 mg/L 7 2010 Results > 0.3 mg/L Highest reading = 0.44 mg/L at #3004 at Vaughn’s Branch, Fayette County 2 nd Highest reading = at K350/#1069 at Hickman Creek, Fayette County
Sulfate (SO 4 ) Can be picked up as groundwater moves through sulfate-containing minerals in bedrock. Drinking water with high sulfate levels can cause diarrhea & dehydration in people and animals. Drinking Water Supply Std. = 250 mg/L No 2010 Sulfate results > 250 mg/L Highest reading of 208 mg/L at #2929 at Calloway Creek, Madison County
Chlorides Chlorine + Metals = Chloride Salts • Drinking Water Supply Std = 250 mg/L • Chronic Aquatic Life Std = 600 mg/L • Acute Aquatic Life Std = 1,200 mg/L 1 reading > 267 mg/L at #3019 at Vaughn’s Branch, Fayette County
Conductivity Measure of total dissolved solids or ability of water to carry an electrical current. • Levels directly affect aquatic life support (negative impacts observed at 300-500) • Can serve as indicator of sewage input • Ohio River Std = 800 micromhos/cm • EPA’s proposed Central Appalachia Std = 300 micromos/cm 5 2010 results > 800 micromhos/cm
High (Lab) Conductivity Sites K054 / #793 – 902 micromhos/cm McConnell Springs, Fayette County K307 / #1028 – 899 micromhos/cm Wolf Run, Fayette County #2929 – 1098 micromhos/cm Calloway Creek, Madison County #2977 – 914 micromhos/cm Cove Spring, Boyle/Mercer County #3019 – 1,500 micromhos/cm Vaughn’s Branch, Fayette County
Metals Summary 28 metals analyzed at lab 0 detections for 13 of these 28 metals 14 of the 28 metals associated water quality criteria When no detection of metal, result entered as ½ of MDL (minimum detection level) ½ MDL of Cadmium, Lead, Thallium > Water Quality Standard – NO violation
Metals with Water Quality Criteria Antimony – no detections Arsenic – no detections Barium – no water quality standard violations Beryllium – no detections Cadmium – no detections Chromium – no detections Copper – 2 sites > chronic AL (#1139 and #3019) Iron – 9 sites > DWS, 3 sites > chronic AL Lead – no detections Nickel – no water quality standard violations Selenium – no detections Silver – no detections Thallium – no detections Zinc – no water quality standard violations
2010 Sites of Concern K005 (#744)—Cane Run, Scott County (field dissolved oxygen, pathogens) K072 (#811)—Steele’s Branch, Fayette County (field conductivity, phosphorus) K264 (#990) - Unnamed tributary, Madison County (field conductivity, pathogens) K307 (#1028) - Wolf Run, Fayette County (field conductivity, pathogens) K350 (1069) - Hickman Creek, Fayette County (field conductivity, phosphorus)
2010 Sites of Concern K606 (#1270) - Unnamed Tributary, Lincoln County (field dissolved oxygen, pathogens) K643 (#1307) - Jessamine Creek, Jessamine County (field dissolved oxygen, pathogens) 2976—Mocks Creek, Boyle County (field dissolved oxygen/conductivity, pathogens) 2993—West Hickman Creek, Fayette County (pathogens, phosphorus) 3004, 3019– Vaughn’s Branch, Fayette County (field conductivity, pathogens, phosphorus)
Sites of Concern for Pathogens K184, K464, K466, K468, K471, K517 - Wolf Run, Fayette County (includes Springs Branch and Vaughn’s Branch) K309 (#1030) - McKecknie Creek, Garrard County
Questions & Discussion Anyone present have a 2010 Site of Concern? Is there any local watershed activity addressing the concerns? Other questions about sampling results and their meanings?
Recent Developments • TMDL Reports – Submitted to KYDOW • South Elkhorn Pathogen TMDL • Cane Run Pathogen TMDL – Schedule to be completed by 6/30/2011 • Town Branch/Wolf Run TP TMDL • Cane Run TP TMDL • Eagle Creek Pathogen TMDL • UK EPA Center of Excellence for Watershed Mgmt. – Approved by EPA (Fall 2010) – Official Launch (Spring 2011) • KWRRI Annual Meeting (March 21, 2011)
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