Thi s im Co-creation in Wind works JEC Paris 2014 Luuk Groenewoud, DSM Luc Peters, 3B-the fibreglass company Page 0
DSM Mission Our purpose is to create brighter lives for people today and generations to come. We connect our unique competences in Life S ciences and Materials S ciences to create solutions that nourish, protect and improve performance. Page 1 1
DSM Global Presence North America: 33 locations China: 4,000 employees 31 locations 3,000 employees Europe: 64 locations 13,000 employees India: 8 locations 700 employees Latin America: 15 locations World total: 1,000 employees 200+ locations 22,000 employees Page 2
DSM Composites Means Innovation for Sustainability Cobalt Free Zero Styrene Renewable GMP Increased health Performance and Long term supply End user product and safety sustainability by security, Reduced safety through through reduction and environmental Good substitution of elimination of impact through Manufacturing soon-to-be listed styrene emission replacement Practice (GMP) Ingredients by and smell of raw materials for Composite greener by renewable components in alternatives alternatives contact with Food and Drinking water Page 3
3B-the fibreglass company A reference in fibreglass for quality and innovation Maj or and dynamic actor in composite reinforcement solutions • A large product range of reinforcement s for thermoplastic, thermoset and specialty glass fibers for numerous applicat ions wit h a special focus on specific market segment s: thermoplastics, wind energy, performance composites • Three manufacturing plants: Birkeland (Norway), Battice (Belgium) and Goa (India) • R&D center in Belgium • Dedicated marketing, commercial and t echnical organizations • 950 employees building upon a long herit age of expertise 4
unique glassfibre solutions high performance and eco-responsible Innovating and setting new standards wit hin the fibreglass industry 5
partnering with customers to develop today’ s innovation and tomorrow’ s products • 3B’ s values of proximity and reliability , our high level of service and responsiveness , as well as our ability to innovate , are of great benefit for our customers • Providing partners with a value proposition beyond the product itself such as innovative tailor-made solut ions for a specific cust omized sizing, packaging and logistics for example 6
Wind Energy Markets are Anticipated to Grow Page 7
Significant Portion Installed in China Source: GWEC Page 8
Tough Requirements Wind Energy • Reliable wind turbine operat ion • Generat e energy wit hout int erruption • Low investment cost • Minimal maintenance • Long and efficient working life Page 9 Page 99
Current Material Systems for Wind Turbine Blades Have Limitations • Mostly based on epoxy resins – Bring resist ance t o fat igue – Yet sensit ive t o process variations – Require a t ime-consuming post -cure for reaching opt imum physical properties • Blades based on polyester resins have important share of market – Resins are easier to process – But laminates feature less fatigue resist ance – Typically based on styrene-cont aining resins, requiring appropriate emission cont rol systems in blade production Page 10 10
Composites Industry is Dealing with Several Challenges at the Same Time • Desire for higher performance material systems – Excellent mechanical propert ies – Large production series capability – Improved process consist ency and quality (e.g. less repairs) • Desire to have alternatives to styrene – St yrene is most commonly used react ive diluent – S trong smell, need for emission cont rol – Flammability • Replacement of t raditional Cobalt cat alysts used for curing – Cobalt Octoat e already classified as CMR2 – Fut ure classificat ion yet unclear • Reduce dependence on fossil-based raw materials – Event ual depletion fossil resources – Price volatilit y Page 11
Breakthrough Beyone™ 201-A-01 Resin from DSM • Can be employed in high end applications and compete with epoxy resins on performance • Reactive diluent derived from renewable feedstock • Works perfectly with a new, Cobalt-free catalytic system based on BluCure™ Technology Page 12
Properties of Beyone™ 201-A-01 Resin Can Compete with those of Epoxy Resin K 1 C Tensile Tensile Elongation Flexural Flexural Casting Tg Density (MPa � m) strength modulus at break Strength Modulus ( ° C) formulation (g/cm³ ) (MPa) (GPa) (% ) (MPa) (GPa) Beyone™ 201-A-01 1.48 77 3.4 6.3 124 3.7 111 1.12 Epoxy reference 1.02 78 3.1 4.7 123 3.4 89 1.18-1.20 UPR reference 0.66 60-90 3-4 2-10 90-120 3-4 60-150 1.15 Page 13
Benefits of Beyone™ 201-A-01 Resin • Excellent mechanical performance, incl. fatigue resistance • Wit h all the benefits of UPR processing • Low viscosity – quick infusion • Fast and adj ust able hardening at room t emperat ure • No or limit ed post -cure (dependent on process set up) • Close to 40% derived from renewable sources • Close-to-zero emissions as resin is 100% styrene-free • Has low labeling, marginal smell before and no smell after curing • The resin utilizes sustainable, Cobalt free curing technology (based on BluCure™ Technology) Page 14
Composite Properties Rely on Interface of Fibre and Matrix High mechanical performance: int erface Glass fibre needs optimal compatibilit y & durabilit y S izing R esin Optimum fibre/ matrix interface properties required • Wet t ing abilit y Poor adhesion Good adhesion • Adhesion performance Fiber debonding Cohesive failure Page 15
Breakthrough SE 3030 Glass Fibre Rovings from 3B • Novel sizing enables excellent wetting of fibres and laminate quality • Great adhesion between fibre and matrix • Enhanced fatigue performance – Increase more t han 10 t imes vs. tradit ional sizings • Meeting Epoxy system benchmark for the Wind Energy market • Improved inter-fibre properties and Inter-Laminar S hear S trength Page 16
Transverse Tensile Strength UD Laminates is Good Indication for Resilience UD fibers Page 17
Adhesion to the Fibre Crucial for Laminate Performance Transverse Transverse Post-cure ILSS Tensile Flexural Laminate based on conditions (MPa) Strength Strength (MPa) (MPa) Beyone™ 201-A-01 (Pure UD Filament 4h @ 40 ° C 65 49 52 Wound) Epoxy reference 90 ° C (Pure UD Filament 4h @ 62 49 49 Wound) Comparable properties at reduced post-cure Page 18
Excellent Laminate Appearance Crack Beyone™ 201-A-01, Beyone™ 201-A-01, Epoxy reference, Glass fabrics Pure UD Filament Wound Pure UD Filament Wound Good impregnation, no dry spots, low fiber visibility Page 19
Co-creation in Wind works Winner 2014 JEC Innovation Award DSM, Siemens Wind Power, 3B, DTU Wind Energy Page 20
Sustainable Material Solutions for Wind Turbine Blades • Reliable wind turbine operation through stronger blades • Increased blade production output – Easy impregnat ion t hrough low viscosit y – Minimal repair and dry spots – Minimal post -cure result ing in reduced mould occupat ion t ime • Reduction in blade manufacturing cost – Lower exot herm result ing in longer mould life • Healthier environment during material processing • S tyrene-free, Cobalt-free (BluCure™ Product), 40 % bio-based – No cost ly emission and air cont rol systems – Healt hier and more enj oyable working environment Page 21
Excellent Resistance to Fatigue for Long-life Blade Performance Page 22
Thi s im Beyone™ 201-A-01 resin has Reduced Eco-Footprint Page 23
Outstanding Value and Sustainability through Co-Creation • Channel partners taking on the challenge together • Complementary expertise to create robust composite system for blade manufacturing • Peace-of-mind on sustainable turbine operation and on sustainable mat erials used • Increasing competitiveness of Wind Energy Page 24 24
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