L&I Maritime Ltd UK company formed 1999 UAE company formed in - PDF document

3/10/2010 L&I Maritime Ltd L&I Maritime Ltd L&I Maritime Ltd L&I Maritime Ltd Unit 4, First Floor Unit 4, First Floor Old Brewery Yard Old Brewery Yard Worksop Worksop Nottinghamshire Nottinghamshire S80 2DE S80 2DE UNITED KINGDOM UNITED KINGDOM Tel: +44 (0) 1909 532 003 Tel: +44 (0) 1909 532 003 Fax: +44 (0) 1909 500 945 Fax: +44 (0) 1909 500 945 Email: operations@limaritime.com Email: operations@limaritime.com L&I Maritime Ltd • UK company formed 1999 • UAE company formed in 2006 • Providing chemical expertise to the industry • Tank Cleaning / Cargo Tank Inspection • Cargo Handling • Training • Projects – laboratory to field (MarinSpec Associates, formed 2007) 1

3/10/2010 L&I Maritime Ltd • Principals are ship owners, charterers, oil majors chemical suppliers industry majors, chemical suppliers, industry organisations and coating manufacturers • APC have employed the services of LIM to investigate the positive impact of MarineLine i ti t th iti i t f M i Li on cargo handling and tank cleaning between different cargo grades Absorption / Transmission • We identified two immediate areas for investigation: investigation: i.) The absorption of penetrating chemical cargoes and transmission into subsequent cargoes This project is well underway (via MarinSpec Associates) and APC have been encouraged to publish the interim results in the near future 2

3/10/2010 Cleanability ii.) The “cleanability” of MarineLine compared ii ) Th “ l bilit ” f M i Li d to other cargo tank linings This project is still in its early stages, but the initial results are interesting and I am pleased to discuss them with you today l d t di th ith t d Cleanability • Our first intention was to explore how MarineLine responded to basic tank cleaning MarineLine responded to basic tank cleaning methods, compared to other commonly used cargo tank linings • Different linings possess different characteristics / advantages and we needed to see where MarineLine fitted in t h M i Li fitt d i • These characteristics always need to be considered when planning any tank cleaning operation) 3

3/10/2010 Cleanability • Organic coatings tend not to absorb viscous (oil based) cargoes, but do absorb (and (oil based) cargoes, but do absorb (and retain) solvent type cargoes • Inorganic coatings (zinc silicate based) are porous and whilst they do absorb solvent type cargoes, do not retain them. Viscous cargoes can and do “stick” to the profile d d “ ti k” t th fil • Stainless steel extremely versatile but with some limitations Cleanability • With this in mind, the following project was developed developed • Five cargo tank linings would be directly compared against each other: i.) i.) Stainless steel Stainless steel ii.) Industry standard zinc silicate (aged) iii.) Industry standard phenolic epoxy iv.) Industry standard high solids ph. epoxy v.) MarineLine 784 4

3/10/2010 Cleanability • Test panels * of each lining would be immersed in the following cargoes for 48 immersed in the following cargoes for 48 hours: Palm Stearin at 65 o C i.) Hydro-cracker Bottoms (HCB) at 50 o C ii.) iii.) iii.) FAME (SBO based) at 30 o C FAME (SBO based) at 30 C Ethylene Dichloride (EDC) at 30 o C iv.) v.) Styrene Monomer at 30 o C * Where appropriate the panels were post cured according to the manufacturers specifications Cleanability • After immersion, the panels were cleaned according to the Dr Verwey tank cleaning according to the Dr. Verwey tank cleaning guide. Hot (70 o C) S/W for 6 cycles PS and HCB: Hot F/W 0.05% Teepol for 4 cycles Cold F/W for 1 cycle Steaming 5

3/10/2010 Cleanability Warm (50 o C) S/W for 6 cycles FAME: H t (70 o C) F/W f Hot (70 o C) F/W for 3 cycles 3 l Steaming EDC: Cold S/W for 3 cycles Warm (50 o C) S/W for 3 cycles ( ) y Steaming Styrene: Cold S/W for 9 cycles F/W flush, then steaming Cleanability • After cleaning, all test panels were “wall washed” with 20ml of methanol washed with 20ml of methanol • Any contamination on the surface of the test panels or absorbed into the coating, would be washed into the methanol. (Contact time is minimal so accurate analysis was required ) minimal, so accurate analysis was required.) • This methanol was scanned in the UV region of the light spectrum using the L&I WAVE II Spectrometer 6

3/10/2010 Cleanability • Theoretically, the test panels with the cleanest wall wash samples could be considered as the wall wash samples could be considered as the easiest to clean … Results palm stearin 1.5 1 5 a b so rb a n ce 1.0 phenolic epoxy high solids epoxy marineline 784 0.5 stainless steel zinc silicate 0.0 200.0 220.0 240.0 260.0 280.0 300.0 320.0 340.0 wavelength (nm) 7

3/10/2010 Results hydro-cracker bottoms 1 5 1.5 absorbance 1.0 phenolic epoxy high solids epoxy marineline 784 0.5 stainless steel zinc silicate 0.0 200.0 220.0 240.0 260.0 280.0 300.0 320.0 340.0 wavelength (nm) Results fatty acid methyl ester (soya) 1 5 1.5 absorbance 1.0 phenolic epoxy high solids epoxy marineline 784 0.5 stainless steel zinc silicate 0.0 200.0 220.0 240.0 260.0 280.0 300.0 320.0 340.0 wavelength (nm) 8

3/10/2010 Results ethylene dichloride (edc) 0.5 0 5 0.4 absorbance 0.3 phenolic epoxy high solids epoxy 0.2 marineline 784 stainless steel 0.1 zinc silicate 0.0 200.0 220.0 240.0 260.0 280.0 300.0 320.0 340.0 wavelength (nm) Results styrene monomer 1 0 1.0 0.8 absorbance 0.6 phenolic epoxy high solids epoxy 0.4 marineline 784 stainless steel 0.2 zinc silicate 0.0 200.0 220.0 240.0 260.0 280.0 300.0 320.0 340.0 wavelength (nm) 9

3/10/2010 Discussion • Clearly, the choice of cargo tank lining does impact on tank cleaning impact on tank cleaning • Viscous cargoes are retained in the zinc silicate coating • Solvent cargoes are retained in the organic Solvent cargoes are retained in the organic coatings • Stainless steel and MarineLine behave almost the same Discussion • Over-cleaning is perhaps apparent? • More efficient tank cleaning procedures can be investigated using this model • Removing absorbed solvent residues from organic coatings and viscous cargoes from zinc silicate 10

3/10/2010 Economic Advantages • Extremely difficult to quantify the economic advantage of M/L because it depends on too many factors: i.) how the vessel is equipped ii.) how many tanks can be cleaned simultaneously iii.) ability of the officers / crew iv.) the duration of the ballast leg / permitted time • What is apparent is that M/L does not seem to absorb penetrative chemical cargoes, nor does it allow viscous oil based cargoes to stick to its surface. In other words it possesses the advantages of both inorganic and organic coatings words, it possesses the advantages of both inorganic and organic coatings. i.) significantly quicker cleaning from oil based cargoes compared to zinc silicate ii.) no challenge of removing absorbed cargoes from organic coatings iii.) reduced need for tank cleaning chemicals. lower tank cleaning costs and less environmental impact iv.) significantly less risk of contaminating subsequent cargoes from retained residues, because there are no retained residues Thank You L&I Maritime Ltd L&I Maritime Ltd Unit 4, First Floor Old Brewery Yard Worksop Nottinghamshire S80 2DE S80 2DE UNITED KINGDOM Tel: +44 1909 532 003 Fax: +44 1909 500 945 Email: operations@limaritime.com 11