STAR European Conference 2010, London Urea Injection and Preparation in Diesel Applications Multiphase Multicomponent Modeling using Star-CD Institute for Powertrains & Automotive Technology Dipl.-Phys. Simon Fischer Dr. Thomas Lauer Institute for Powertrains & Automotive Technology
Contents The SCR-Process: Problem Introduction Methodology and Analysis Setup Thermodynamic Multicomponent Model of a Urea-Water-Solution Droplet-Wall-Interaction and Liquid Film Dynamics Conjugate Heat Transfer and Liquid Film Boiling Ammonia Homogenization Conclusion and Outlook STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 2
Contents The SCR-Process: Problem Introduction Methodology and Analysis Setup Thermodynamic Multicomponent Model of a Urea-Water-Solution Droplet-Wall-Interaction and Liquid Film Dynamics Conjugate Heat Transfer and Liquid Film Boiling Ammonia Homogenization Conclusion and Outlook STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 3
Problem Introduction: Future Diesel Emission Limits Particle Emissions [g/km] [1] SCR NO x - Emissions [g/km] source: Auto News exhaust aftertreatment of NO x is a major requirement for future Diesel engines STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 4
Principle of Selective Catalytic Reduction (SCR) exhaust gas flow (NO x ) exhaust pipe ammonia (NH 3 ) vapour homogenization heat transfer impingement film transport injection of a preparation process water-urea mixture 1) water evaporation 32.5 mass-% urea 2) chemo-physical urea 67.5 mass-% water decomposition to ammonia (thermo-/hydrolysis) CFD-simulation for efficient SCR-system design SCR-catalyst: „NO x +NH 3 →N 2 + H 2 O“ timescales of ammonia preparation ammonia uniformity at catalyst frontal area STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 5
Contents The SCR-Process: Problem Introduction Methodology and Analysis Setup Thermodynamic Multicomponent Model of a Urea-Water-Solution Droplet-Wall-Interaction and Liquid Film Dynamics Conjugate Heat Transfer and Liquid Film Boiling Ammonia Homogenization Conclusion and Outlook STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 6
Methodology and Validation Setup CFD mesh according to urea-water- experimental setup solution-injection SCR-Catalyst exhaust gas flow straight exhaust pipe from engine Analysis of Representative Operating Points (OP): OP1 - low temperature / mass flow / NO x raw emission OP2 - intermediate temperature / mass flow / NO x raw emission OP 3 - high temperature / mass flow / NO x raw emission STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 7
Contents The SCR-Process: Problem Introduction Methodology and Analysis Setup Thermodynamic Multicomponent Model of a Urea-Water-Solution Droplet-Wall-Interaction and Liquid Film Dynamics Conjugate Heat Transfer and Liquid Film Boiling Ammonia Homogenization Conclusion and Outlook STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 8
Thermodynamic Multicomponent Model (Liquid Film, Droplets) Partial Pressures (Raoult`s law): , T i pure i ( ) ( ) p T x p T Boil (Y urea ) s i s Total Pressure (Dalton`s law): i p ( T ) p ( T ) tot s i pure water: pure urea: Antoine saturation equation pressure curve AdBlue: implemented in implemented in 32.5 Mass.-% Urea, dropro.f, lqfpro.f dropro.f, lqfpro.f 67.5 Mass.-% Water STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 9
Decomposition of a Single Urea-Water-Solution-Droplet water evaporation urea thermolysis [1] heat flux through fibre, fine tuning of urea-p sat -curve two-step preparation process modeled [1] Wang, Baek,Lee: Experimental Investigation on Evaporation of Urea-Water-Solution Droplet for SCR Applications, AICE 2009 STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 10
Contents The SCR-Process: Problem Introduction Methodology and Analysis Setup Thermodynamic Multicomponent Model of a Urea-Water-Solution Droplet-Wall-Interaction and Liquid Film Dynamics Conjugate Heat Transfer and Liquid Film Boiling Ammonia Homogenization Conclusion and Outlook STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 11
Multiphase Modeling: Challenge Of Timescales Small Time Scales: Large Time Scales: turbulent flow field liquid film formation and -dynamics droplet dynamics ammonia formation from film species (ammonia) transport wall cooling (CHT) Solution Strategy: Transient Calculation (Simple) Steady-State Calculation (PISO) thermodynamics (enthalpy) fluid flow field droplets and liquid film temperature field Restart with species (ammonia, water vap.) no spray injection (liquid phase) flow field solvers time steps: 0.1 ms (droplets present) switched off 1 ms (otherwise) simulated interval of several minutes incl. spray dynamics and species transport STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 12
Droplet Dynamics: Injection three hole nozzle no primary break-up modelled diameter distribution from droico.f measurement timescale miliseconds STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 13
Droplet Impingement Regimes depending on liquid properties, droplet dynamics, wall temperature ,… Bai-Model (Sw30) Spread-Model OP1 - low temp OP2- medium temp. OP 3 – high temp. … complex behaviour STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 14
Liquid Film Formation: Validation Experiment Simulation Spread- Simulation Bai- Model Model- Switch 30 (Videoanalysis) OP 1 extensive liquid not observed x film, flow to pipe („ cold “) in simulation bottom OP 2 thin film after x („medium“) some delay, no remarkable flow OP 3 x („ hot “) no permanent film impingement model not yet predictive across whole temperature range STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 15
Simulated Liquid Film Formation OP1- Spread massive liquid film with spread model in OP1 OP1-BaiSw30 OP2-BaiSw30 OP3-Bai-Sw30 no permanent film in OP3 transient behaviour in OP2 small extent liquid film with Bai model in OP1 … STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 16
Droplet Impingement and Liquid Film Dynamics high Film Droplet Diameter Thickness liquid film spread after 120 s timescale milliseconds timescale minutes low STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 17
Liquid Film Dynamics Validation Distribution of Liquid Film after 120 Seconds excellent description of film dynamics Video-Analysis [2] Experiment 90° 180° Simulation Simulation 90° 180° OP1- Spread STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 18
Contents The SCR-Process: Problem Introduction Methodology and Analysis Setup Thermodynamic Multicomponent Model of a Urea-Water-Solution Droplet-Wall-Interaction and Liquid Film Dynamics Conjugate Heat Transfer and Liquid Film Boiling Ammonia Homogenization Conclusion and Outlook STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 19
Thermal Wall Boundary Conditions In Star-CD SCR-Modeling Heat Transfer Relevance in Temperature Resistance Conjugate Fixed with Adiabatic Fixed !!! wall as a heat source cooling of wall due to !!! evaporation !! thermal inertia of wall !! wall parallel heat conduction STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 20
Meshing For Conjugate Heat Transfer Approach extruded solid cells for CHT single layer approach fluid cells boundary Layer trimmed from custom-grid STAR European Conference 2010 Urea Injection and Preparation in Diesel Applications March 23rd 2010 | London | Simon Fischer | Slide 21
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