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BIONICO B IOGAS MEMBRANE REFORMER FOR DECENTRALIZED H 2 PRODUCTION - PowerPoint PPT Presentation

Mar 24, 2024 •223 likes •458 views

1 BIONICO B IOGAS MEMBRANE REFORMER FOR DECENTRALIZED H 2 PRODUCTION Call: H2020-JTI-FCH-2014-1 Topic: FCH-02.2-2014 Decentralized hydrogen production from clean CO 2 -containing biogas 24/09/2018 Disclosure or reproduction without prior

  1. 1 BIONICO B IOGAS MEMBRANE REFORMER FOR DECENTRALIZED H 2 PRODUCTION Call: H2020-JTI-FCH-2014-1 Topic: FCH-02.2-2014 Decentralized hydrogen production from clean CO 2 -containing biogas 24/09/2018 Disclosure or reproduction without prior permission of BIONICO is prohibited

  2. 2 S UMMARY BIONICO aims at developing a novel reactor configuration at a larger scale to produce H 2 from biogas production power plant based on:  Design, develop and test a new concept reactor integrating hydrogen production and purification on a single unit  Design, develop and testing of a catalytic membrane reactor for the production of highly-purity hydrogen from biogas, scaling up new H 2 selective membranes and catalyst production  Develop a flexible system (including the advance control and BoP components) capable of producing pure hydrogen from biogas of different composition s in a unique reactor system. The main idea of BIONICO is to design and demonstrate an efficient biogas-to-hydrogen conversion system at real plant conditions using process intensification. 24/09/2018 Disclosure or reproduction without prior permission of BIONICO is prohibited

  3. 3 C ONCEPT 24/09/2018 Disclosure or reproduction without prior permission of BIONICO is prohibited

  4. 4 W HY B IONICO ? h Offgas 0.52 C ONVENTIONAL S YSTEM REFORMER PSA HT-WGS LT-WGS SR / ATR ( H 2 Purification ) (350°C) (200°C) (800°C) HYDROGEN Sulphur BIOGAS PLANT Removal M EMBRANE R EACTOR (500-600°C) Retentate h >0.70 Reference Case Results units SR ATR Two reference cases (based on SR and Biogas feed Nm 3 /h 39.5 63.5 Total Biogas Input kW 229 368 ATR) are identified to benchmark the System efficiency % LHV 51.7 27.8 performance of the BIONICO concept Hydrogen delivery bar 20 20 pressure Hydrogen € /kg 4.21 6.37 production cost The target of BIONICO is a system efficiency above 70% LHV , which is about 25% higher than SR (52% LHV ). The higher efficiency together with equipment savings will end up in lower hydrogen production costs. 24/09/2018 Disclosure or reproduction without prior permission of BIONICO is prohibited

  5. 5 P ARTNERSHIP Multidisciplinary and complementary team: 8 top level European organisations from 7 countries including 3 Research Institutes and Universities and 4 representative top industries in different sectors (from catalyst to membranes to chemical and process engineering, etc.)  POLIMI, Italy  TU/e, The Netherlands  Abengoa, Spain  Tecnalia, Spain  ICI caldaie, Italy  Johnson Matthey, UK  ENC Energy, Portugal  Rauschert, Germany  Quantis, Switzerland 24/09/2018 Disclosure or reproduction without prior permission of BIONICO is prohibited

  6. 6 W ORK STRUCTURE 24/09/2018 Disclosure or reproduction without prior permission of BIONICO is prohibited

  7. 7 P ARTNERSHIP S YNERGIES ICI ICI ICI ICI ICI 24/09/2018 Disclosure or reproduction without prior permission of BIONICO is prohibited

  8. 8 N OVEL C ATALYST G OAL Development of highly active reforming catalysts to produce hydrogen from diverse biogas mixture coupled with steam and air in a fluidised bed regime. T HREE Y EARS P ROJECT A CTIVITIES  PGM doped alumina catalysts have been tested under biogas reforming conditions for dry, steam or autothermal reforming  Coke formation resistance improvement A CHIEVEMENTS  1 st generation catalyst and 2 nd generation catalyst able to work under fluidisation regime and at low temperature  Final Catalyst formula produced and shipped to ICI 24/09/2018 Disclosure or reproduction without prior permission of BIONICO is prohibited

  9. 9 N OVEL M EMBRANE & S UPPORT G OAL Development of Pd based tubular supported membranes, for application in biogas reforming catalytic membrane reactors T HREE Y EARS P ROJECT A CTIVITIES  Preparation of porous ceramic tubes of different diameters and materials for their use as supports for thin Pd-based membranes  Manufacturing of thin film (<5 µm thick) Pd-Ag and Pd-Ag-Au membranes on top of the ceramic supports.  Development of new finger-like porous asymmetric ceramic supports in which one of the ends of the tube is a closed porous part. Finger-like asymmetric porous ceramic supports 24/09/2018 Disclosure or reproduction without prior permission of BIONICO is prohibited

  10. 10 N OVEL M EMBRANE & S UPPORT G OAL Development of Pd based tubular supported membranes, for application in biogas reforming catalytic membrane reactors A CHIEVEMENTS  1 st generation membrane & support  Installation of a new plating system for preparation of >40 cm long membranes.  2 nd generation membrane & support. Thin Pd-Ag layers have been deposited onto  2 nd generation thin film Pd-alloy supported the 50 cm long finger-like supports. membranes (>40 cm long)  Definition of criteria for support quality  Improvement of manufacturing procedure for membrane prototype production  Membranes for prototype preparation 24/09/2018 Disclosure or reproduction without prior permission of BIONICO is prohibited

  11. 11 L AB S CALE R EACTOR G OAL Definition of the lab scale reactors performances and identification of the best design for prototype pilot. T HREE Y EARS A CTIVITIES  Selection and characterization of the membrane for the prototype Study of long-term membrane performance in a fluidized bed;  The effect of H 2 S on the performance of PdAg and PdAgAu membranes are  studied  Obtain a comprehensive description of the catalyst reaction kinetics  Design and demonstration of biogas steam reformer at Lab-scale  Development of phenomenological model of the fluidized-bed membrane reactor 24/09/2018 Disclosure or reproduction without prior permission of BIONICO is prohibited

  12. 12 L AB S CALE R EACTOR G OAL Definition of the lab scale reactors performances and identification of the best design for prototype pilot. A CHIEVEMENTS  Integration of catalyst and membrane  One dimensional phenomenological model of the reactor  Effect of Au addition on H 2 S resistance of the membrane 1 E505 PdAg 0.9 Perm H2S /Perm 0 (-) E505 PdAgAu (5%au) 0.8 Model E506 PdAgAu (7%au) 0.7 0.6 0.5 0.4 0.3 0 10 20 H 2 S [ppm] 24/09/2018 Disclosure or reproduction without prior permission of BIONICO is prohibited

  13. 13 L AB S CALE R EACTOR G OAL Definition of the lab scale reactors performances and identification of the best design for prototype pilot. A CHIEVEMENTS  Successful description of concentration polarization in the reactor model  Lab scale system with 5 membranes equal to the once that will be used in the pilot, as well as the catalyst, have been tested 24/09/2018 Disclosure or reproduction without prior permission of BIONICO is prohibited

  14. 14 P ROTOTYPE R EACTOR G OAL Final design and construction of MR prototype for the production of approximately 100 kg/day of pure hydrogen T HREE Y EARS P ROJECT A CTIVITIES  Preliminary design of the prototype catalytic membrane reactor at large scale including control system design  Preliminary design of the balance of plant 24/09/2018 Disclosure or reproduction without prior permission of BIONICO is prohibited

  15. 15 P ROTOTYPE R EACTOR G OAL Final design and construction of MR prototype for the production of approximately 100 kg/day of pure hydrogen A CHIEVEMENTS Retentate PURE ATR-MR HYDROGEN  A techno-economic optimization of BIONICO H 2 Vacuum Pump HX-4 system was assessed HX-2 Air+H 2 O CMP BG  Different operating conditions (T, p, S/C), Air brn BIOGAS biogas compositions and permeate side Exhaust Burner Sep configuration were investigated HX-1 HX-0 Sep  Membrane reformer designed and water rec. Air ATR manufactured by ICI H 2 O CMP Air H 2 O feed P-1 24/09/2018 Disclosure or reproduction without prior permission of BIONICO is prohibited

  16. 16 I NTEGRATION &T ESTING AT B IOGAS P RODUCTION S ITE G OAL Final evaluation of the innovative process to directly produce pure hydrogen in a real biogas production site (ENC Landfill plant) T HREE Y EARS P ROJECT A CTIVITIES  Definitions of input needed for starting the plant licensing procedure  Evaluating the integration of the prototype reactor in the overall BIONICO system at biogas production site Landfill plant Biogas cleaning unit 24/09/2018 Disclosure or reproduction without prior permission of BIONICO is prohibited

  17. 17 L IFE C YCLE A SSESSMENT & S AFETY I SSUES G OAL Development strategy towards sustainable solutions and provide guidance on how to operate the reactor prototype under safe conditions. T HREE Y EARS P ROJECT A CTIVITIES  Refined goal & scope of LCA analysis, in particularly, with further clarifications with regard to: (i) reference systems (baseline), i.e., SMR and ATR, (ii) level of details of inventory modeling and (iii) system boundaries  Improved data collection for key data points, especially related to functional unit, biogas input, conversion efficiency, energy and water use as well as direct GHG emissions during conversion processes  Final LCA analysis between BIONICO CMR and reference technologies  In progress of developing applicable safety protocol 24/09/2018 Disclosure or reproduction without prior permission of BIONICO is prohibited

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